轻度热解条件对霍林河褐煤水分复吸性能影响的研究.docVIP

　　 　 　　　 　 A—化学工程与技术　 作者简介：叶普海（1989—），男，四川绵阳人，硕士研究生，从事煤炭洁净综合利用技术研究。HYPERLINK TelelE-mail:yphs@163.com　　 轻度热解条件对霍林河褐煤水分复吸性能影响的研究　　　 叶普海1，周敏1，刘恭欣2，钱春梅1，等 杨絮 杨絮1，陈恒宝1　　 （1.中国矿业大学 化工学院，煤炭加工与高效洁净利用教育部重点实验室，江苏 徐州 221116　 2. 新疆天池能源有限责任公司，新疆 昌吉831100）　　 摘要：为研究提质褐煤的再吸水能力，将轻度热解提质后的霍林河褐煤置于25℃饱和空气中吸水，通过分析提质褐煤水分复吸达饱和过程中水分随时间变化的动态特性曲线，考察不同热解温度，恒温时间对提质褐煤水分复吸性能的影响，并通过cubic插值法采用MATLAB仿真得到提质褐煤复吸饱和水分的分布图，提出参照Langmuir吸附模型建立提质褐煤复吸水分随时间变化的动力学方程。试验结果表明：不同热解条件所得提质褐煤水分复吸的曲线大致相同，相比恒温时间，热解温度对提质褐煤的水分复吸影响更明显，提质褐煤水分复吸的动力学方程为:。　 关键词：褐煤；热解；提质；复吸性能；动力学　 Study on the effects of pyrolysis conditions on the re-adsorption property of Huolinhe lignite 　 (1.Key laboratory of Coal Processing and Efficient Utilization, Ministry of Education, School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, Jiangsu China 　　　 2. Xinjiang Tianchi Energy limited liability company, Changji 831100, Xinjiang China)　　　 Ye Pu-hai1，Zhou Min1，Liu Gong-xin1，Qian Chun-mei1，et al Yang Xu1，Chen Heng-bao Yang Xu1，Chen Heng-bao1　　 Abstract：In order to research the re-adsorption property of upgraded lignite, the upgraded Huolinhe lignite was put in a 25℃ saturated air environment after mild pyrolysis. Through analysis the dynamic characteristic curves of water changes with time in the course of moisture adsorption up to saturation. Influences of different pyrolysis temperature and constant temperature time to the re-adsorption property of upgraded lignite were investigated. Distributing graph of the re-adsorption saturation moisture of upgraded lignite were obtained with cubic interpolation by MATLAB simulation. Kinetic equation was built to describe the variation of moisture with time of upgraded lignite referring to Langmuir adsorption model. The results show that the re-adsorption curves of upgraded lignite in different pyrolysis conditions are approximately same. Compared with constant temperature time, the pyrolysis temperature has significant influence