sub-doppler spectroscopy by use of microwave sidebands of co2 laser lines applied to the c-o stretching fundamental band of methanolsub-doppler光谱利用微波显然二氧化碳激光线应用于切断拉伸基本的甲醇.pdfVIP

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sub-doppler spectroscopy by use of microwave sidebands of co2 laser lines applied to the c-o stretching fundamental band of methanolsub-doppler光谱利用微波显然二氧化碳激光线应用于切断拉伸基本的甲醇.pdf

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sub-doppler spectroscopy by use of microwave sidebands of co2 laser lines applied to the c-o stretching fundamental band of methanolsub-doppler光谱利用微波显然二氧化碳激光线应用于切断拉伸基本的甲醇

Molecules 2003, 8, 92- 102 molecules ISSN 1420-3049 Sub-Doppler Spectroscopy by Use of Microwave Sidebands of CO Laser Lines Applied to the C -O Stretching Fundamental 2 Band of Methanol Zhen-Dong Sun, Toru Mizuochi, Masanori Kaneko, Yoshiki Moriwaki, Fusakazu Matsushima and Kojiro Takagi Department of Physics, Toyama University, Toyama 930-8555, Japan Abstract: Microwave sidebands of CO2 laser lines were used as an infrared source in infrared microwave double resonance spectroscopy and infrared saturation spectroscopy to study the C -O stretching fundamental band of methanol. In the former application, rotational lines in the v = 1 state have been observed with good signal to noise ratios and physical CO processes involved in this metho d have been discussed. In the latter method, (vt, A/E, K) = (2, A, 4) sequence transitions in the C-O stretching fundamental band have been identified and term values for the (2, A, 4) levels in the v = 1 state have been determined. CO Keywords: Sub-Doppler spectroscopy, methyl alcohol, infrared. Introduction Microwave sidebands of CO laser lines are useful infrared sources for spectroscopy in the 10-m 2 region due to their tunability, high power and high spectral purity. In this paper two applicatio ns related with saturated absorption to the spectroscopy for the C-O stretching fundamental band of the methanol molecule are reported: (1) infrared- microwave double resonance spectroscopy an