一种高分散性富锌漆的制备及性能研究-表面技术.PDFVIP

摇 第42卷摇 摇 第6期摇 摇 2013 年12 月 表面技术 摇 摇 摇 Vol.42摇 No.6摇 Dec.2013 SURFACE TECHNOLOGY 摇摇 101 一种高分散性富锌漆的制备及性能研究 1 1 1 2 2 邓静伟 ,唐囡 ,尹桂来 ,刘志雷 ,刘光明 (1.国网江西省电力科学研究院,南昌330096;2. 南昌航空大学,南昌330063) 摘摇 要: 目的摇 提高锌粉在富锌漆中的分散性。 方法摇 利用硅烷偶联剂KH550 与过量环氧树脂E鄄44 反 应制备长链分散剂,之后与锌粉砂磨接枝,制得高分散性锌浆液;以有机膨润土与气相二氧化硅作为防沉 剂,在二甲苯+正丁醇混合溶剂中高速分散后,加入改性锌浆和其它助剂,高速搅拌制得富锌漆A组份;B 组份为聚酰胺650 固化剂。 将A,B组份混合,制备涂层,测试涂层的性能。 结果摇 加入分散剂后,漆膜附 着力由不加分散剂时的2级升高到1级,柔韧性由3 mm减小为2 mm,抗冲击性能由30 kg ·cm提高到50 kg ·cm,电化学阻抗性能提升1倍以上。 结论摇 由高分散性涂料制备的富锌涂层具有良好的综合性能。 关键词:富锌漆;偶联剂;分散剂 中图分类号:TQ630.6摇 摇 摇 文献标识码:A摇 摇 摇 文章编号:1001鄄3660(2013)06鄄0101鄄05 Study of Preparation and Properties of High Dispersed Zinc鄄rich Coating 1 1 1 2 2 DENGJing鄄wei ,TANGNan ,YIN Gui鄄lai ,LIUZhi鄄lei ,LIUGuang鄄ming (1.State GridJiangxi Electric Power Research Institute,Nanchang330096,China; 2.Nanchang Hangkong University,Nanchang330063,China) ABSTRACT:Objective摇 To improve the dispersion of zinc in zinc鄄rich coating. Methods摇 Thehigh dispersedzinc slurry was prepared by zincpowder anddispersant,whichwasobtainedbythereactionbetween KH550 andepoxy un鄄 der sanded conditions. The part A of zinc鄄rich coatingwasfirst prepared by mixing bentonite and aerosol in dimethyl鄄 benzene and butanol under high stirring conditions,thentheprior preparedzinc slurry and other auxiliary agentswere addedandstirred. Part Bof zinc鄄richcoatingwaspolyamide650 dissolvedinmixedsolvents. PartAandBwerefinal鄄 ly mixed to make the coating. Results摇 Comparing the properties of the coatings with or without the dispersant,we f