辐射一步法制备聚丙烯酰胺聚苯乙烯纳米微球复合水凝胶.PDFVIP

第40 卷 第1 期 核 技 术 Vol.40, No.1 2017 年1 月 NUCLEAR TECHNIQUES January 2017 辐射一步法制备聚丙烯酰胺/聚苯乙烯 纳米微球复合水凝胶 樊文慧 刘汉洲 文万信 （苏州大学医学部放射医学与防护学院江苏省放射医学与防护学院重点实验室 苏州 215123 ） 摘要 利用辐射乳液一步法将聚苯乙烯引入到水凝胶中，合成载有聚苯乙烯纳米微球的复合水凝胶。利用傅 里叶变换红外光谱和X 射线光电子能谱表征了材料的化学结构；扫描电子显微镜分析表征复合水凝胶的表面 结构；通过对水和生理盐水的吸收能力来评估复合材料的吸附能力。实验结果表明，辐照形成的聚苯乙烯纳 米微球被成功地复合到水凝胶的框架结构上，获得的复合水凝胶具有优异的吸水和吸盐水性能。 关键词 水凝胶，辐照聚合，一步法，聚苯乙烯微球 中图分类号 TL75 DOI: 10.11889/j.0253-3219.2017.hjs.40.010301 Polyacrylamide composite hydrogel with polystyrene nanospheres prepared by one-step irradiation-induced method FAN Wenhui LIU Hanzhou WEN Wanxin (School of Radiation Medicine and Protection, Medical College of Soochow University, Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection , Suzhou 215123, China) Abstract Background: Polyacrylamide hydrogel plays an important role in many areas. There also has been growing interest in polyacrylamide hydrogel modification by polymerizing and crosslinking methods, introducing different groups to obtain various functions. Purpose: The aim is to propose a novel one-step irradiation-induced polymerizing and crosslinking method to prepare polyacrylamide (PAAm) composite hydrogel with polystyrene (PS) nanospheres. Methods: The chemical structures of PAAm composite hydrogel with PS nanospheres were measured by Fourier transform infrared spectroscopy (FTI