常压水热法下钛白石膏的脱水速率与产物形貌-环境工程学报.PDFVIP

第 11卷　 第5 期 环 境 工 程 学 报 Vol. 11,No.5 2 0 1 7 年 5 月 Chinese Journal of Environmental Engineering May 2 0 1 7 常压水热法下钛白石膏的脱水速率与产物形貌 赵辉,张群朝,蒋涛,任小明∗ 湖北大学材料科学与工程学院,有机化工新材料湖北省协同创新中心,功能材料绿色制备与应用教育部重点实验室,武 汉430062 摘　 要　 采用常压水热法将工业副产钛白石膏转化为晶体形貌规整的α-半水钛石膏,利用 XRD确定了反应产物的相态组 成,利用 TGA 分析了不同条件下不同时刻产物的结晶水含量,利用 SEM 观测了不同条件下得到的产物晶体形貌,掌握了不 同的工艺参数对钛白石膏的脱水速率及其产物形貌的影响。 研究结果表明:随着氯化钙含量增加,钛白石膏脱水速率逐渐 加快,当氯化钙含量为 15%时,40 min 内其脱水程度可以达到90% 以上,并获得规整的六棱短柱状晶体;而反应物浓度对 钛白石膏脱水速率和产物晶体形貌影响不大,但浓度过大时,会造成晶体轻微团聚;随着反应温度的升高,钛白石膏脱水速 率加快,当温度为 100 ℃时,40 min 内其脱水程度可以达到90%以上,产物呈现规整的六棱短柱状晶体;溶液 pH值对钛白 石膏脱水速率影响不大,但可以影响晶体的形貌,当pH值为5 时,产物呈现规整的六棱短柱状晶体。 关键词　 钛白石膏;α-半水钛石膏;常压水热法;转晶剂;晶体形貌 中图分类号　 X705　　 文献标识码　 A　　 文章编号　 1673-9108(2017)05-3030-06　　 DOI　 10.12030/ j.cjee.201606032 Dehydrating rate of titanium gypsum and crystal morphology of α-hemihydrate titanium gypsum by atmospheric hydrothermal method ZHAO Hui,ZHANG Qunchao,JIANG Tao,REN Xiaoming∗ Key Laboratory of Green Preparation and Application for Functional Materials, Ministry of Education, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials,Faculty of Materials Science Engineering,Hubei University,Wuhan 430062,China Abstract　 The α-hemihydrate titanium gypsum was prepared from titanium gypsum through atmospheric hydro- thermal method,XRD test wasused to analysisthe phase composition of the products,TGA test wasused to anal- ysis the crystal water content of products at different time and conditions,SEM test was used to observe the mor- phology of products. Effects of different factors on the dehydrating rate of titanium gypsum and the crystal mor- phology of α-hemihydrate titanium gypsum were investigated. The results show that,the dehydrating rate of tita- nium gypsum increased gradually as the increase of the calcium chloride, when calcium chloride content was 15% by mass,the dehydrating rate of titanium gyp