污水处理厂脱水污泥中重金属的分布规律-河海期刊.PDF

第30卷第2期 水摇 资摇 源摇 保摇 护 2014年3月 Vol.30 No.2 WATER RESOURCES PROTECTION Mar.2014 DOI:10.3969/ j.issn.1004 6933.2014.02.013 污水处理厂脱水污泥中重金属的分布规律 徐摇 骏,朱摇 伟 (河海大学环境学院,江苏 南京摇 210098) 摘要:针对污泥中重金属赋存形态尚不明确的问题,使用MacNicol提出的组分分离方法,以3 个污 水处理厂污泥为对象,研究了重金属在无机颗粒、生物絮团、胶粒、流动相4 个组分中的分配情况。 结果表明,脱水污泥的干物质中颗粒组分和生物絮团组分约占到了67% ~94%,而在脱水污泥中 颗粒组分和生物絮团仅占7% ~22%,大多数属于流动相。 这一组成特性决定了脱水污泥的大部 分重金属分布在污泥流动相中,无机颗粒、生物絮团、胶粒中的重金属只占很少一部分。 但从赋存 浓度来看,流动相重金属浓度很低,相反有机相胶粒组分中重金属浓度较高。 关键词:脱水污泥;组分分离法;重金属分布;污水处理厂 中图分类号:X505摇 摇 摇 文献标志码:A摇 摇 摇 文章编号:1004 6933(2014)02 0062 05 Distribution of heavy metals in dewatered sludge from wastewater treatment plant XU Jun,ZHU Wei (College of Environment,Hohai University,Nanjing 210098,China) Abstract:As thechemical speciationof heavy metalsinthesludgefromawastewatertreatmentplantisundefined, we used the MacNicol component separation method to study the allocation of heavy metals in four components (inorganic particulate,biological floc,colloid,and the mobile phase) in the sludge of three wastewater treatment plants. Theresultsshowthattheparticulatecomponentandbiologicalfloccomponentinthedrymatterof dewatered sludge accounted for approximately 67% to 94% of the total quantity of the dry matter,while the particulate component andbiologicalfloccomponentindewateredsludgeaccountedforonly7% to22% ofthetotalquantity of the sludge,whichwasmostlyinthemobilephase. Thesecomponentcharacteristicsdeterminethedistributionofthe majority of heavy metals in the dewatered sludge in the mobile phase, and the heavy metals in the inorganic particulate,biologicalfloc,andcolloidaccountforonly asmallpart. Asfortheconcentrationsoftheheavymetals, the hea