鞍山铁矿区土壤稀土元素地球化学特征研究-吉林农业大学学报.PDF

吉林农业大学学 2011，04 Journal of Jilin Agricultural University E-mail:jlndxb@ 鞍山市铁矿区土壤稀土元素地球化学特征研究∗ ∗∗ 孙 超，李月芬 ，王冬艳，董会和，郭冬艳 吉林大学地球科学学院，长春 130061 摘 要：为探明鞍山铁矿区土壤稀土元素地球化学背景，以鞍山市铁矿区土壤为研究对象，从稀土元素的全量特征 和分馏特征两方面进行了系统研究。结果表明：齐大山区和大孤山区土壤稀土元素总量均值分别为 195.50 mg/kg和 278.57 mg/kg ，均高于中国大陆土壤中稀土元素的含量(187.60 mg/kg) ；大孤山区∑REE平均含量明显高于齐大山区， 并且每项稀土元素的含量都高于齐大山区；2 区内ΣCe/ΣY值均＞1，分馏比值(La/Yb)N ＞(La/Sm)N ＞(Gd/Yb)N ，δEu ＜1，δCe接近 1；土壤中稀土元素含量遵循奥多— 哈金斯法则，含量分布基本保持一致，土壤中轻重稀土元素分馏 明显，呈现轻稀土元素相对富集；Ce元素无异常，Eu元素亏损。 关键词：土壤；稀土元素；地球化学特征；铁矿区；辽宁省鞍山市 中图分类号：S153.6 文献标识码： 文章编号：1000-5684 （2011 ） DOI: 网络出版地址： Geochemical Characteristics of Rare-Earth Elements in the Soils around Iron Mine Regions of Anshan SUN Chao，LI Yue-fen，WANG Dong-yan ，DONG Hui-he，GUO Dong-yan College of Earth Sciences，Jilin University ，Changchun 130061，China Abstract ：A systematic study of the total analysis and fractionation characteristics to identify the geochemical characteristics of the soils at iron mine region in Anshan was conducted. The results indicated that the mean content of soil rare-earth elements of Qidashan and Dagushan was 195.50 mg/kg and 278.57 mg/kg, respectively. The value of ∑REE and each item of rare earth elements content in Dagushan were higher than in Qidashan. In the two regions the value of ΣCe/ΣY was higher than 1, (La/Yb)N ＞(La/Sm)N ＞(Gd/Yb)N ，δEu value was lower than 1, and δCe value was near 1. The content of REE followed the Oddo - Harkin rule strictly. LREE and HREE separated obviously, showing LREE relative enrichment. Ce showed no anomaly and Eu showed negative anomaly. Key words：soil; REE; geochemical characteristics; iron mine region; Anshan city of Liaoning province 稀土元素由镧系及与镧系性质相似的钇、钪共