咔唑超临界抽提及蒽油绿色加工工艺研究.pdf

I 500 300~360 255 7MPa 0.0257g/mL 270 12MPa 68% 270~280 12~18MPa 64%~70% 280 15MPa II Abstract More than 10 thousand kind of organic compounds were contained in coal tar, about 500 of them were identified. Up to now, coal tar was the only source of many fused ring compounds and heterocyclic compounds with O N S. Anthracene fraction was switched off within the temperature range (300 ~ 360 ) when coal tar distillated. The main components of anthracene oil anthracenepheneanthrenen carbazole were widely used in chemical medicine dye pesticide carbon, etc. It was of important social significance and commercial values to develop and research environmentally energy-savingefficient processing technology which had been one of the important areas concerned in Cokery Industry. Supercritical fluid extraction which was an efficient and clean separation technology get a lot of attention in coal tar processing applications field according to the requirement of environment protection, energy saving and high efficiency in - energy chemical.In this paper ,supercritical ethanol was used as the solvent to extract monocomponent of carbazole , simulated anthracene oil and commercial anthracene oil with the method of constant volume heating up , studying the law and mechanism in supercriti