近红外光谱法快速测定速生桉木化学成分含量-国家林业局桉树研究.PDF

第32 卷 第3 期 桉树科技 Vol.32 No.3 2015 年9 月 EUCALYPT SCIENCE TECHNOLOGY Sep.2015 近红外光谱法快速测定速生桉木化学成分含量 ＊ 吴 珽，房桂干 ，梁 龙，崔宏辉，邓拥军 ( 中国林业科学研究院 林产化学工业研究所；江苏省 生物质能源与材料重点实验室；国家林业局 林产化学工程重点开放性实验室； 生物质化学利用国家工程实验室，江苏 南京 210042) 摘要：用常规方法测定了104 个速生桉木样品的综纤维素、聚戊糖、酸不溶木素及苯醇抽出物含量并采集了样品 的近红外光谱。对原始光谱进行多元散射校正后，运用偏最小二乘法和交互验证的方法,确定最佳主成分数并建立 样品相关化学成分含量的校正模型。独立验证中综纤维素、聚戊糖、酸不溶木素和苯醇抽出物模型的决定系数Rval2 分别为0.906 7、0.903 3、0.950 4 、0.957 0 ；预测均方根误差(RMSEP)分别为0.33%、0.50%、0.31%、0.17% ；相 对分析误差(RPD)值分别为3.22、3.20、4.43 、4.73 ；绝对偏差(AD)分别为−0.53% ~ 0.60%、−0.95% ~ 0.77%、−0.55% ~ 0.52%、−0.22% ~ 0.29%，4 个校正模型较好地预测了验证集样品的化学成分含量，基本满足制浆造纸工业中快 速测定速生桉木原料的需求。 关键词：近红外光谱法；速生桉木；偏最小二乘法；化学成分 中图分类号：O657.3 ；TS721 文献标识码：A Rapid Prediction of Chemical Components in Fast-growing Eucalyptus by Near Infrared Spectroscopy WU Ting, FANG Gui-gan, LIANG Long, CUI Hong-hui, DENG Yong-jun (Institute of Chemical Industry of Forestry Products , CAF; Key Lab. of Biomass Energy and Material , Jiangsu Province ; National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. on Forest Chemical Engineering , SFA, Nanjing 210042, Jiangsu , China) Abstract : A study was conducted to use the conventional method to analyze the content of holocellulose, pentosan, lignin and benzene-alcohol extractive content of 104 fast-growing Eucalyptus wood samples and the near-infrared (NIR) spectra were also collected. After the original spectra were subject to multiplicative scatter correction (MSC), partial least squares (PLS) method and cross-validation were used to confirm the best factors. Based