【精选】GC_MS内标法测定土壤中多环芳烃的质量控制.pdfVIP

25 4 Vol . 25 No . 4 2011 12 Arid Environmental Monitoring Dec . . 2011 GCPMS , , ( , 114004) : GCPMS : ; 7. 80% ~ 25. 2% 49. 2% ~ 96. 6% ; 7. 77% ~ 19. 8% 67. 2% ~ 122% ; 0. 05~ 0. 08 mgPkg , : GCPMS; ; ; : X83015 : B : 1007- 1504( 2011) 04- 0230- 08 Quality Control on the Determination of Polycy clic Aromatic Hydrocarbons in Soil by Internal Standard Method of GCPMS TIAN ing, ZHONG Yan, YANG Hong- biao( Anshan Environmental Monitoring Center, Anshan Liaoning 114004, China) Abstract: The paper described the basic elements, basic methods and basic operation of quality control that internal standard method of GCPMS was employed for determining PAHs in the soil. The results showed that blank result was less than detection limit. Spiked blank precision was from 7. 80% to 25. 2% , accuracy was from 49. 2% to 96. 6% . And spiked samples precision was from 7. 77% to 19. 8% , accuracy was from 67. 2% to 122% . Detection limit was from 0. 05 mgPkg to 0. 08 mgPkg. The results of determination were scientific, accurate, and could meet the test requirements. Key words: GCPMS; soil; PAHs; quality control ( PAHs) , , , , 80 , , , GCPMS , , , P( QAPQC) [ 1] [ 2- 8] , GCP MS ( ) 7 : ¹GCPMS ; º GCPMS , , , ; » : 2011- 06- 14; : 2011- 10- 11 : ( 1975- ) , , , , , 4 GCPMS # 231 # ; ¼; ½ , ; ¾; ¿ ( GR) 500 e 2 h [ 2] 1.