结果与讨论-南京林业大学.DOC

天然水源水中DBP紫外降解效果和机理研究 ，， （南京林业大学 工程学院，江苏研究了254nm紫外光照射条件下DBP降解效果机理。结果表明，紫外强度和初始浓度通过改变单位浓度BP所获得的光子能量影响降解效果，溶液pH对降解效果没有影响。单纯紫外照射对DBP去除效果相对较差，在低浓度条件下较为适用，这主要是因为DBP降解主要依靠其自身直接光解，在初始浓度10mg/L左右，紫外强度0.62W/L条件下，紫外照射6h的降解效率最高能达85%。低腐殖酸条件下，DBP紫外降解符合一级反应动力学添加腐殖酸条件下的反应速率变小，说明腐殖酸对DBP的吸附作用较其作为光敏物质增加降解效率的能力强。机理研究表明DBP降解主要从侧链开始，后进一步降解为苯甲酸等中间体，最后降解为二氧化碳和水。 ：邻苯二甲酸二丁酯降解腐殖酸机理 TQ043; X522 文献标识码：A 文章编号： Ultraviolet degradation of Dibutyl phthalate in aqueous solution simulating the natural water sources LIN Zi-zeng, GU Tian-wei, ZHONG Tao，FENG Jun-kai, XU Jian ( Civil College of Nanjing forestry university, Nanjing 210037,china) Abstract: The degradation and mechanism of dibutyl phthalate （DBP） in aqueous solution was investigated under 254nm ultraviolet radiation. The results showed the effect was affected by UV intensity and the initial concentration which could change the photon energy of unit DBP, while the pH had no effect on the degradation efficiency. DBP removal effect of UV irradiation was relatively poor, which was more applicable in low concentration range, and it was primarily because the DBP degradation rely on its own direct photolysis. The degradation efficiency of UV irradiation during 6h could up to 85% in initial concentration of about10 mg/L and UV intensity of 0.62W/L. The degradation of DBP was in accordance with the negative first order kinetics under the condition of low humic acid, the reaction rate became smaller in the addition of humic acid, which showed that the adsorption effect of humic acid on DBP was stronger than increasing the degradation efficiency of humic acid as the photosensitive material. Mechanism study showed that DBP degradation was mainly degraded from the side chain, the next step was to degrade the intermediates such as benzoic acid, and degraded to carbon dioxide and water finally Key word: Dibutyl phthalate; Ultraviolet degradation; Humic acid; Mechanism 作者简介：-），男，山东潍坊人实验，主要工程教学与科研工作邮箱：ccitlin@163.com.电话： 基金项目:邻苯二甲酸酯类化合物（PAEs）是一