聚碳酸酯奶瓶中双酚A单体向食品模拟物迁移规律的研究.PDFVIP

246 2011, Vol. 32, No. 12 食品科学 ※分析检测 A 1 1 2 1 郭春海 ，陈瑞春 ，赵安康 ，马育松 (1.河北出入境检验检疫局，河北 石家庄 050051 ；2.安徽大学化学化工学院，安徽 合肥 230039) 研究用食品模拟物浸泡聚碳酸酯奶瓶中双酚 A 的迁移规律，高效液相色谱法检测模拟物中双酚A ，外标 法定量。从添加回收率、精密度及线性关系等方面进行相应的方法学研究，模拟物添加量 0.1 ～10 μg/mL 时，回 收率为77.0%～98.7%、变异系数为5%～9.8%，在双酚A 的质量浓度为0.1～10μg/mL 时相关系数r ＝0.99996 。根 据该方法和欧盟有关模拟物规定的指令，检测了聚碳酸酯奶瓶中双酚 A 在不同模拟物和不同时间内的迁移率。 聚碳酸酯；奶瓶；双酚 A ；高效液相色谱法(HPLC) ；食品模拟物；迁移规律 Migration of Biphenol A from Polycarbonate Milk Bottle to Food Simulants 1 1 2 1 GUO Chun-hai ，CHEN Rui-chun ，ZHAO An-kang ，MA Yu-song (1. Hebei Entry-Exit Inspection and Quarantine Bureau, Shijiazhuang 050051, China ； 2. College of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China) Abstract：In order to explore the migration of biphenol A from polycarbonate milk bottles to foods, polycarbonate milk bottles were soaked in four food simulants such as distilled water, 3% acetic acid solution, 15% ethanol solution and olive oil for 3 days and the content change of biphenol A in the food simulants after 1, 2 and 3 days of soaking was detected by high performance liquid chromatography using an external standard method. The recovery rate, accuracy and linear relationship of the developed method were studied. At 0.1, 1 and 10 μg/mL spike levels, the recovery rates were 77.0% －98.7% with a variant coefficiant of 5%－9.8%. A good linear relationship was observed over the range of 0.1 to 10μg/mL with a correlation coefficient of 0.99996. This method has been satisfactorily used to determine migration rates of