微乳液介质中Br-PADAP光度法测定CuⅡ.PDFVIP

22 4 矿　冶　工　程 Vol.22 №4 2002 12 MINING AND META URGICA ENGINEERING December 2002 5-Br-PADAP Cu(Ⅱ) 1 1 2 1 1 1 侯曼玲, 代　军, 唐贤军, 沈广鑫, 杨辉华, 谭秀丽 (1. , 410083;2., 250000) 　:///, Cu(Ⅱ) 2-(5--2-)-5- (5-Br-PADAP)。 1 mol/L NaAc , Cu(Ⅱ)5-Br-PADAP , 550 4 nm, 9.53×10 L/(mol·cm), 0～8μg/25 mL 。Cu (Ⅱ), 。 :;;;; The 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol Photometric Method for the Determination of Copper in Microemulsion Media 1 1 2 1 1 1 HOU Man-ling , DAI Jun , ANG Xian-jun , SHEN Guang-xin , YANG Hui-hua , AN Xiu-li (1.College of Chemistry and Chemical Engineering , Central South University , Changsha 410083, Hunan, China ; 2.J inan Iron -steel Co L td, j inan 250000, S handong , China ) Abstract:he indicative reaction of copper (Ⅱ)with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol in the medium of an- ionic microemulsion of Sodium dodecyl sulphate /n-Butanol /n-Heptane/Water was studied.In 1mol/L NaAC medium, the reagent reactswith Cu(Ⅱ)to form a stable orange complex, the maximum absorption of the complex lie at 550 nm with a mo- 4 -1 -1 lar absorptivity of 9.53 ×10 L·mol ·cm .Beer law is obeyed in the range of 0 ～8 μg/25 mL.he proposed method has been applied to the determination of microamounts of Cu(Ⅱ)in sinterore and common steel with satisfactory results. Key words:copper;sinter ore;common steel;microemulsion;spectrophotometry 　　 :0.1000 g (99.95% , ),5 mL HNO3 (1+1), , [1～5] 。2-(5--2-)-5- ( 100 mL,,1 mL 1 mg。 5-Br-PADAP) 1 μg/mL 。 [6] ,OP 5-Br