纤维膜脱硫组合技术在液化石油气脱硫脱硫醇中应用.pdf

学兔兔 石 油 与 天 然 气 化 工 第44卷 第 4期 CHEMICAL ENGINEERING OF OILGAS 19 纤维膜脱硫组合技术在液化石油气脱硫脱硫醇中的应用 孙守华 中化泉州石化有限公司 摘 要 介绍了纤维膜脱硫组合技术在某石化公司液化石油气脱硫脱硫醇装置上的工业应用情 况。结果表明，纤维膜脱硫组合技术具有适用性强、开工过程简单等优点。脱硫脱硫醇后催化裂化装置 液化石油气中总硫质量浓度降至16．3～16．8 mg／m。，铜片腐蚀等级为la，延迟焦化装置液化石油气中 总硫质量浓度降至50．8～77．8 mg／m。，铜片腐蚀等级为la，均满足产品质量要求。经过水洗后，两装 置循环碱性洗水中硫化物质量浓度分别为17．91 mg／L和73．83 mg／L，回收大量副产物二硫化物；废 碱液经过碱液再生后，碱液质量分数均大于15 ，满足纤维膜脱硫醇的需要。碱渣经过湿法氧化处理 后，满足排放标准。 关键词 纤维膜 液化石油气 脱硫 脱硫醇 应用 中图分类号：TE868 文献标志码：B DOI：10．3969／j．issn．1007—3426．2015．04．004 Application of the fiber film desulfurization combination technology in removing sulfide and mercaptan from liquefied petroleum gas Sun Shouhua (Sinochem Quanzhou Petrochemical Co．，Ltd，Quanzhou 362103，ChinⅡ) Abstract：The industrial application of the fiber film desulfurization combination technology in liq— uefied petroleum gas sweetening unit in a petrochemical company was introduced The result indicated ． that the fiber film desulfurization combination technology had the advantages of great applicable activ— ity and simple starting—up．The total sulfur content in liquefied petroleum gas in fluid catalytic crack— ing unit may reduce to 16．3—16．8 mg／m。after sweetening；and the corrosion grade of copper sheet was l a．The total sulfur concentration of liquefied petroleum gas in delayed coking unit may reduce to 5O．8—77．8 mg／m。，and the corrosion grade of copper sheet was la．meeting th