基于热耦精馏三组分混合烷烃分离工艺.pdf

石 油 化 工 · 862 · PETR0CHEMICALTECHNoLOGY 2015年第44卷第7期 基于热耦精馏的三组分混合烷烃分离工艺 杨德明，王 颖，谭建凯，高晓新 (常州大学 石油化工学院，江苏 常州 213164) [摘要]采用AspenPlus化工流程模拟软件，选用RK—Soave方程计算物性数据，以分离过程的年总费用 (ATC)最低为 目标函 数，对侧线精馏热耦工艺 、侧线提馏热耦工艺和完全热耦精馏工艺用于三组分混合烷烃的分离进行模拟。模拟结果表明，侧 线精馏热耦工艺、侧线提馏热耦工艺和完全热耦精馏工艺分别需要274，293，142块塔板；侧线精馏热耦工艺比侧线提馏热 耦工艺塔板少l9块，但能耗增加14．98％；完全热耦精馏工艺比侧线提馏热耦工艺的能耗降低24．32％；完全热耦精馏工艺比侧 线精馏热耦工艺和侧线提馏热耦工艺的ATC分别减少34．35％和23．08％；完全热耦精馏工艺的塔板数、能耗和ATC最低。 [关键词]混合烷烃；热耦精馏；分离工艺；模拟；能耗；三元物系 [文章编号]1000—8144(2015)07—0862—05 [中图分类号]TQ028 [文献标志码 ]A SeparationofTernarySystemsBasedonThermallyCoupledDistillation Deming，WangYing，TanJiankai，GaoXiaoxin (CollegeofPetrochemicalEngineering，ChangzhouUniversity，ChangzhouJiangsu213164，China) lAbstractJAimedattheminimizationoftheannualtotalcost(ATC)forseparatingternaryalkane mixtures，thermallycoupleddistillationwithsiderectifying，themr allycoupleddistillationwithside strippingandfullythermallycoupleddistillationweresimulatedandoptimizedbymeansoftheAspen PlussoftwarewiththeRK—Soaveequation．Theresultsshowedthatthethreedistillationprocesses needed274plates，293platesand 142plates，respectively,Thethemr allycoupleddistillationwith siderectiyfingsaved19platesbutitsenergyconsumptionincreasedby14．98％comparedwiththe thermallycoupleddistillationwith sidestripping．Thefullythermallycoupleddistillationcanreduce energyconsumptionby24．32％ comparedwiththethermallycoupleddistillationwithsidestripping， andcanreduceATCby34．35％ and23．08％ comparedwiththethemr allycoupleddistillationwith siderectiyfingandthethermallycoupleddistillationwithsidestripping，respectively．Sotheplate number，energyconsumptionandATC ofthefullythermallycoupleddistillationprocessarethe lowest． 1Keywordsjmixedalkanes；themra