M. 金属间化合物与高熵合金-2011中国材料研讨会.doc

M. 金属间化合物与高熵合金 分会主席：林均品、贺跃辉、张勇 单元M1：2011年5月19日上午 主持人：张勇 8：30---9：00 am *M1 TiAl金属间化合物精密热成形技术研究进展 陈玉勇； 哈尔滨工业大学 9：00---9：30 am *M2 NiAl合金高温自润滑行为及其机理研究 郭建亭； 中科院金属材料研究所NiAl-Al2O3-TiC复合材料、NiAl-28Cr-5.6Mo-0.15Hf-0.25Ho共晶合金和NiAl-Cr(Mo)-CrxSy自润滑复合材料的高温摩擦磨损实验结果表明，NiAl材料在700~900℃下，摩擦表面生成1~3μm厚的玻璃陶瓷润滑膜，产生高温持久自润滑耐磨性能。该润滑膜可向SiC表面转移，形成玻璃陶瓷/玻璃陶瓷的摩擦状态，消除NiAl材料与SiC之间的直接磨损。润滑膜的形成与摩擦表面温度有重要关系。当摩擦表面温度达到镍的剧烈氧化温度时，表面的NiAl材料生成Ni、Al、Cr等氧化物颗粒，而脱离表面的NiAl材料磨屑在SiC盘的反复碾压下，也很快发生断裂、碎化和动态氧化而生成Ni、Al、Cr等氧化物粉末，并通过摩擦化学反应形成玻璃陶瓷润滑膜覆盖在摩擦表面。200~400℃下，NiAl-Cr(Mo)-CrxSy自润滑复合材料中的CrxSy型共晶体化合物相可变软或熔化，在磨损过程中，形成由纳米CrxSy型共晶体化合物晶粒构成的较完整的润滑膜覆盖在摩擦表面，具有自润滑性能。该润滑膜也可向SiC表面转移，消除共晶合金与SiC之间的直接磨损。he wear behaviors of NiAl-Al2O3-TiC composite, NiAl-28Cr-5.6Mo -0.15Hf-0.25Ho eutectic alloys and NiAl-Cr(Mo)-CrxSy Self-lubricating Composite against SiC ceramic were investigated. The results show that NiAl-based alloys exhibit excellent high temperature endure self-lubricating properties in the temperature range of 700-900℃, which is attributed to the formation of glass-ceramic lubricant film with the thickness of 1-3 μm. During wear testing the lubricant film was partially transferred to the SiC counterface, which avoided the direct tribo-contact between the alloy and SiC cermic and led to another friction state which friction happened between glass-ceramic and glass-ceramic. The formation of the lubricant film depends on friction surface temperature. When the temperature is high enough to make nickel oxide severely, oxides of element Ni, Al and Cr form on the surface of NiAl-based alloys and from wear debris which divorced from the wear surface. Through friction chemical reaction the oxides form glass-ceramic lubricant film which then overlays the friction surface. CrxSy-type eutectic compound in the NiAl-Cr(Mo)-CrxSy Self-lubricating Composite may soften or melt. Between 200 and 400℃, a relatively intact lubricant film composed of nano CrxSy-type eutectic compound overlays the friction surface and it is a self-lubricant f