改性锌基热硬磷酸盐铸造粘结剂制备.pdfVIP

学兔兔 Aug．2015 Vo1．64 N0．8 ·769· 改性锌基热硬磷酸盐铸造粘结剂的制备 刘伟华，宋 来，李英民，杜 放，王 墅 (沈阳工业大学材料科学与工程学院，辽宁沈阳110870) 摘要：以磷酸和氧化锌为主要原材料，合成了一种锌基磷酸盐粘结剂，通过加热硬化，可获得较高的强度，但吸湿 性很强。因此，采用氧化镁、氢氧化钙和D剂进行了复合改性，取得了良好的效果。本文以砂芯的抗拉强度为考核 指标，通过正交试验优化了各组分的比例，即磷酸溶液：氧化锌：氧化镁：氢氧化钙：D剂=200：52：3：1：8。在粘结剂 加入量3％的情况下，得到砂芯的初始抗拉强度为3．03 IVIPa，抗吸湿性也得到明显的改善。在湿度30％~40％环境下， 24 h抗拉强度为2．53 MPa；在湿度60％~70％环境下，24 h抗拉强度为1．64 MPa；发气量 (850℃x3 min)为10．5 mL／g， 高温残留强度 (800℃x30 min)为0．12 MPa，能够满足一般铸造生产的要求。 关键词：铸造粘结剂；锌基磷酸盐；复合改性 中图分类号：TG221 文献标识码：A 文章编号：1001—4977(2015)08—0769—04 Preparation of a Modified Zinc·Based Baked Phosphate Binder for Foundry LIU Wei—hua，SONG Lai，LI Ying—min，DU Fang，WANG Shu (School ofMaterials Science and Engineering，Shenyang University ofTechnology，Shenyang 1 10870，Liaoning，China) Abstract：In this Pape a zinc．based phosphate binder was firstly prepared with phosphoric acid and zinc oxide as main raw materials，aRer heated a high early strength was gained’but moisture absorption is strong．To overcome the deficiency of strong moisture absorption,phosphate binder was modified with magnesium oxide， calcium hydroxide and D agent to be a compound phosphate binder．The tensile strength ofsand was used as the index and the proportion ofthe components was decided by o~hogonal test as followed：phosphoric acid：zinc oxide：magnesium oxide：calcium hydroxide：D．agent=200：52：3：1：8．、 en the binder addition is 3％．the initial strength ofsand Can be 3．03 MPa,the moisture absorption performance ofsand is significantly improved The 24 h strength Can be 2．53 MPa at a low environmental hum idity 30％一40％：while the 24 h strength can be 1．64 MPa at a higher hum idity 60％一70％：the gas evoluti