电池隔膜论文：等离子体磺化处理碱性二次电池隔膜的研究.docVIP

电池隔膜论文：等离子体磺化处理碱性二次电池隔膜的研究 【中文摘要】本课题利用低温等离子体表面改性技术和磺化技术对碱性二次电池隔膜进行改性处理,分别研究了等离子体引发浓硫酸磺化、等离子体引发发烟硫酸磺化、等离子体引发混合溶液磺化三种不同改性方法对丙纶隔膜的处理效果。分别对丙纶隔膜原样、直接磺化样品、等离子体引发磺化样品进行相关性能测试,系统地研究了各种处理方法所相关的实验参数(磺化温度、磺化时间、磺化浓度等)对电池隔膜改性效果的影响,并对隔膜表面的化学组成和形态结构使用红外光谱、XPS、扫描电镜等仪器手段进行了表征分析。实验结果表明,通过以上三种改性手段,都可以在丙纶(PP)隔膜表面引入磺化基团,从而改善亲水性能、吸碱性能及面电阻。其中:等离子体引发浓硫酸磺化后,PP隔膜的接触角从90°下降到25°,说明亲水性能明显改善;等离子体引发发烟硫酸磺化,PP隔膜的爬高可以达到7.9 cm(5min),吸碱量可以达到272%;等离子体引发混合溶液磺化,爬高可以达到7.6 cm(5min),吸碱量可以达到266%。三种手段改性处理后隔膜面电阻也分别下降了32倍,80倍和65倍;同时不会对隔膜的力学性能有太大的影响。比较各种处理条件对电池隔膜性能的综合影响表明:在反应温度90℃,反应时间3min,混合溶液浓度为16.6%的条件磺化可以使电池隔膜性能得到大幅改善,同时又很好地兼顾了生产成本。 【英文摘要】The surface of polypropylene film was modified by cold plasma treatment for alkali secondary battery separator, which is polypropylene (PP) separator, in this paper. The surface treatment was carried out using three different methods, such as plasma initiate concentrated sulfuric acid sulfonation, plasma initiate fuming sulfuric acid sulfonation and plasma initiate mixture sulfonation, and the treatment effects in battery separator were studied.The related performance of original PP separator, direct sulfonation PP separator and plasma initiating sulfonation PP separator was tested, and the involved treatment parameters of three methods above, including sulfonation temperature, sulfonation time, sulfonation concentration etc, were studied systematically. Equally, IR, XPS and SEM were used to characterize the surface properties of the samples such as chemical composition and morphological structure of material surface.Results reveal that sulfonic acid groups were successfully introduced onto the surface of PP separator using those three methods mentioned above, then separator抯 hydrophilicity, alkali absorption and membrane surface resistance have been improved. The membrane contact angle changed from 90皌o 25皐hen original PP separator was treated using plasma initiating concentrated sulfuric acid sulfonation. When using plasma initiating fuming sulfuric acid sulfonation, the