混凝土盐冻破坏机理Ⅱ冻融饱水度和结冰压.pdf

学兔兔 第 15卷第 6期 建 筑 材 料 学 报 Vo1．15，No．6 2012年 l2月 JOURNAL OF BUII DING MATERIAI S Dee．。2O12 文章编号：1007—9629(2012)06 0741—06 混凝土盐冻破坏机理(Ⅱ ) ： 冻融饱水度和结冰压 杨全兵 (1．同济大学 材料工程研究所，上海 201804； 2．同济大学先进土木工程材料教育部重点实验室，上海201804) 摘要：研究了冻融循环条件下NaC1浓度(质量分数)对混凝土内部吸入溶液量和饱水度、溶液结冰 膨胀率和结冰压的影响，继而对混凝土盐冻破坏机理进行分析．结果表明：随着NaCl浓度的增加， 溶液结冰膨胀率和结冰压平衡值显著降低，但溶液结冰产生结冰压的临界饱水度显著提高；在 NaC1溶液中进行冻融循环时，混凝土内部饱水度明显高于水中，且饱水度的增长主要取决于冷冻 阶段吸入溶液量，与融化阶段关系很小；2 ～6 NaC1溶液将产生最大结冰压，因此中低盐浓度引 起的混凝土盐冻破坏最严重． 关键词：混凝土；盐冻破坏；结冰压；膨胀；饱水度；机理 中图分类号：TU528．0 文献标志码：A doi：10．3969／ ．issn．1007—9629．2O12．06．002 One of Mechanisms on the Deicer-Frost Scaling of Concrete(Ⅱ)： of Saturation and Ice—Formation Pressure during Freezing-Thawing Cycles YANG Quan—bing ’。 (1．Research I．aboratory of Materials Engineering，Tongji University，Shanghai 201804，China；2．Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education，Tongji University，Shanghai 201804，China) Abstract：Effects of NaC1 concentration(by mass)on the solution absorption and degree of saturation in concrete，and the ice～formation expansion ratio and pressure of solutions were investigated under freezing— thawing cycles，and then mechanisms on the deicer—frost scaling of concrete were analyzed．Results show that the equilibrium value of ice——formation expansion ratio and pressure of solutions are significantly re—— duced with the increase of NaCI concentration，but the critical degree of saturation is obviously enhanced． The degree of saturation in concrete during freezing—thawing cycles in NaC1 solutions are obviously higher than