光催化重整碳水化合物制氢.pdfVIP

第八届全国氢能学术会议论文投稿 光催化重整碳水化合物制氢 ∗ 付先亮，王绪绪 ，张子重，苏辉煌，龙金林，付贤智 (福州大学光催化研究所，福州大学，福州，350002) 通过溶胶凝胶法制备了纳米晶 TiO ，并采用浸渍还原法制得相应贵金属负载 TiO 。利用XRD 、DRS 和 N 吸附等 2 2 2 方法表征了催化剂的结构和织构。评价了样品光催化重整糖类产氢性能，包括反应气氛、Pt 负载量、贵金属种类、 生物质投加量和生物质种类等对产氢的影响。结果表明，贵金属修饰对 TiO2 的晶相、比表面积和光吸收的影响不大， 但能大大提高 TiO2 对糖类的产氢活性。Pt 最佳负载量为 1 wt %时，样品对葡萄糖的光催化产氢量最大。在 1 wt%载 量下, 贵金属负载 TiO 重整葡萄糖产氢的活性顺序为: Pt/TiO ≈Pd/TiO ＞Au/TiO ＞Rh/TiO ＞Ag/TiO ≈Ru/TiO 。O 2 2 2 2 2 2 2 2 对葡萄糖的光催化重整产氢具有抑制作用，N2 气氛则有利于产氢。对多糖产氢反应的研究结果表明，所考察的糖类 都能很好的产氢，但产氢速率随着多糖聚合度的增加逐渐降低。葡萄糖投加量的实验表明葡萄糖初始浓度对产氢反 应速率的影响符合 Langmuir-Hinshelwood 关系式。 Hydrogen Production from Carbohydrate by Photocatalitic Reforming Fu Xianliang, Wang Xuxu*, Zhang Zizhong, Su Huihuang, Long Jinlin, Fu Xianzhi (Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002) Abstract: Nano-TiO2 and noble metals-supported TiO2 were prepared by a sol-gel method and an impregnation–reduction route, respectively. The structure and texture of the as-synthesized catalysts were characterized by XRD, UV-Vis-DRS spectroscopy, and N2 adsorption. For glucose, the influences of the reactive atmospheres, the loaded amount of Pt, the type of the loaded metal, and the glucose initial concentration on its reforming into hydrogen were investigated over TiO2 . The hydrogen evolution of other carbohydrate was also compared. The results showed that loading of noble metals could rem