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表面与界面化学试卷(a)2008
武汉理工大学考试试题纸( A 卷)
课程名称 表面与界面化学
专业班级 材化0601,0602
题号
一
二
三
四
五
六
七
八
九
十
十一
十二
总分
题分
8
8
6
14
4
8
8
6
8
30
100
备注: 学生不得在试题纸上答题(含填空题、选择题等客观题
What are chemisorption and physisorption? (6 points)
A fresh mica surface is prepared under three sets of conditions—in air, under argon, and in a vacuum—and the surface energy determined. Will the surface energies determined be equal? If not, rank them in order of increasing value and give your reason for the order chosen. (8 points)
At the beginning of rain, the raindrops slid down the window glass. It can be often seen that the first raindrop can be catch up by the later. Explain this phenomenon. (6 points)
(1) A monolayer of protein spreads at the air?water interface. The amount of protein spread is equivalent to 0.80 mg m-2 and gives a surface tension lowering of 0.035 mN m-1. What is the molecular weight of the protein? (6 points); (2) Given that the CMC of sodium dodecylsulfate (十二烷基磺酸钠)is 8.9mM at 45(C, calculate the expected cmc values for the C-10, C-14, and C-16 members of the homologous series. (8 points)
The HLB values for Sodium oleate and triethanolamine oleate are 18 and 12, respectively. Please point out which one is more soluble in oil? (4 points)
Fig.1
Figure 1 shows an adsorbed structure on an fcc surface. How might this adsorbate structure on the surface be described using Woods notation? What is the coverage of adsorbate for this surface structure??? (8 points) Describe the spreading behaviour you would expect when a drop of benzene is placed on a clean water surface. For the pure liquids the interfacial tensions ( in mNm-1) are: air-water 72.8 air-benzene 28.9 benzene-water 35.0. However small amounts of each liquid slowly dissolve in the other and this affects the interfacial tensions which then become: air-water 62.2 air-benzene 28.8 benzene-water 35.0. (8 points)
Dissociative adsorption of a homonuclear diatomic molecule, A 2 , can be represented by the following chemical equation :
2
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