钢中微量硼的测定方法研究及其对钢淬透性的影响【毕业论文】.docx

钢中微量硼的测定方法研究及其对钢淬透性的影响摘 要硼是一种化学元素,化学符号为 B,硼元素主要是以硼砂等矿石的形态存在，经过研究，人们已经发现微量硼能够显著地提高钢的淬透性。近年来，科学家开始致力于对微量硼影响钢淬透性机理的研究，目前，业界普遍认可的机理是奥氏体晶界能降低机理，硼的加入在确保钢淬透性的前提下，还能够节约贵重金属和稀缺合金，从而大大地节省了钢材的成本。由于钢铁中的硼对钢铁的淬透性有很大的影响，因此，快速而准确地分析出钢铁中硼的含量就显得尤为重要。文中对当前多种主要的分析方法进行了试验总结，比如姜黄素分光光度法、微波消解后 ICP 法和光电直读光谱法，通过对标样和试样进行对比检测，同时，对以上这三种方法进行测定条件的优化，并从准确度、回收率和精密度等方面证实方法的可行性，经过实验的研究，发现不同的样品适用的方法是不同的，对于屑状样品，我们可选择微波消解后ICP 法来检测硼的含量；对于块状样品，我们可采取光电直读光谱法来加以检测，此外，本文通过试验来得到硼的有效浓度范围，最终确定硼的质量分数在 0.0005％～0.0025％范围时，对钢淬透性的影响是最为显著的。关键词：硼，淬透性，姜黄素分光光度法，光电直读光谱法，微波消解后ICP 法ISTUDY ON THE DETERMINATION METHOD OF TRACE BORON IN STEEL ANDITS INFLUENCE ON HARDENABILITYABSTRACTBoron is a chemical element, chemical symbol is B, the content of boron in the earths crust or about 0.001%, which is mainly based on morphological borax and other minerals in the presence of people through a series of studies have found that trace amounts of boron can be significantly improved steel hardenability. Entering the new century, scientists began working on the mechanism of steel quenching effect on trace boron, and after the addition of small amounts of boron, boron rapidly adsorbed at grain boundaries, which filled before depression, thus reducing the bit boundaries, increasing the difficulty of the new nucleation, and ultimately improve the stability of the austenite. Boron added steel hardenability ensuring the premise, but also to save precious metals and rare alloys, which greatly saves the cost of steel. In recent years, trace boron is widely used in the field of plastic mold steel.Because boron steel has a great influence on the steel hardenability, therefore, This paper analyzes the different analytical methods,such as curcuminIIIspectrophotometry has the advantage that it less demanding test equipment, we can choose after microwave digestion ICP method to detect the content of boron, for bulk samples, we can take direct reading photoelectric spectroscopy to be detected, in addition, the paper test