HONO来源及其对空气质量影响研究进展 Advances in HONO sources, HONO simulations, and the impacts of the HONO sources on regional or global air quality.pdfVIP
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HONO来源及其对空气质量影响研究进展 Advances in HONO sources, HONO simulations, and the impacts of the HONO sources on regional or global air quality
中国环境科学2014,34(2):273~281 ChinaEnvironmentalScience
HONO来源及其对空气质量影响研究进展
安俊岭+,李 颖,汤宇佳,陈 勇,屈 玉(中国科学院大气物理研究所,大气边界层物理与大气化学国家重点
实验室,北京100029)
激发态N02与水汽作用形成HONO的机制在高N仉排放地区具有重要作用,但反应速率需进一步证实.非均相反应中水解反应可能是
实验证实;土壤排放机理的外场实验研究极少,亟待加强.
关键词:气态亚硝酸;OH.;氮氧化物;气溶胶:非均相反应
中图分类号:X131.1 文献标识码:A 文章编号:1000—6923(2014)02一0273一09
AdvancesinHONO the
sources,HONOsimulations,and theHONOsourceson or air
impac缸of regionalglobal
Yhlg,TANG of
qnafity.ANJun·ling’,LI Yu-jia,CHENY0ng,QUYu(StateKeyLaboratoryAtmosphericBoundary-
and of of
layerPhysicsAtmosphericChemistry,InstituteAtmosphericPhysics,ChineseAcademy
Environmental
100029,China).China
Science,2014,34(2):273-281
Abstract:HONOHONO and reaction
sources(i。e emissions,homogeneousgas-phaseproductionheterogeneous
the oftheHONOSOurceson or air werereviewed.
production),HONOsimulations,andimpacts regionalglobalquality
in
Reaction withwater contributedmuchtoHONOformationelevatedemissionareasbut
N02 vapor NOx
ofphotoexcited
theaccuratereactionrateneodstobe formationofHONO011wetsurfacescouldbethe
quantified.Heterogeneous key
sourceof Was air modelsimulations.The reductiononsootis
HONO,which
supportedby quality photosensitizedN02
a contributortoHONOconcentrationsin sootemissionareasbuttherelatedfieldstudiesare
possiblylarge high required.
Observationsof emissionsfromsoilare limitedand needed.
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