重氮化合物的亲核环化反应-北京大学工学院.PPT

* * * * * * * * * * * * * 9 * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * 6. 其他相关反应 6.4 (MeO)2POCHN2、重氮甲烷和TMSCHN2的同系化反应 In situ generation of Bestmann-Ohira reagent and synthesis of alkynes Jepsen, T. H.; Kristensen, J. L. J. Org. Chem. 2014, 79, 9423. 6. 其他相关反应 6.4 (MeO)2POCHN2、重氮甲烷和TMSCHN2的同系化反应 Reaction of benzyl or alkyl bromide with Bestmann-Ohira reagent Pramanik, M. M. D.; Chaturvedi, A. K.; Rastogi, N. Chem. Commun. 2014, 50, 12896. 6. 其他相关反应 6.4 (MeO)2POCHN2、重氮甲烷和TMSCHN2的同系化反应 Ireland-Claisen rearrangement of cyclopropenylcarbinyl esters and sequential esterification Ernouf, G.; Brayer, J.-L.; Folle?as, B.; Demoute, J.-P.; Meyer, C.; Cossy, J. Org. Lett. 2015, 17, 3786. Synthesis of α,β-unsaturated diazoketones from aldehydes and HWE reagents Pinho, V. D.; Burtoloso, A. C. B. J. Org. Chem. 2011, 76, 289. 6. 其他相关反应 6.5 α-羰基重氮阴离子和亲电试剂的其他反应 Mechanism of coupling of α-diazoketones with thiourea Yadav, J. S.; Reddy, B. V. S.; Rao, Y. G.; Narsaiah, A. V. Tetrahedron Lett. 2008, 49, 2381. Synthesis of β-ketoesters from lithiated diazo esters with acylsilanes Galliford, C. V.; Scheidt, K. A. Chem. Commun. 2008, 1926. 6. 其他相关反应 6.5 α-羰基重氮阴离子和亲电试剂的其他反应 Reaction mechanism of formal [3+2+1]-cycloaddition from azomethine imines Xu, X.; Xu, X.; Zavalij, P. Y.; Doyle, M. P. Chem. Commun. 2013, 49, 2762. 6. 其他相关反应 6.5 α-羰基重氮阴离子和亲电试剂的其他反应 Formal [4+1] annulation of α-halo N-acyl hydrazones with α-diazoesters Attanasi, O. A.; De Crescentini, L.; Favi, G.; Mantellini, F.; Mantenuto, S.; Nicolini, S. J. Org. Chem. 2014, 79, 8331. 6. 其他相关反应 6.5 α-羰基重氮阴离子和亲电试剂的其他反应 Substrate-dependent reaction of isolable dialkylsilylene with diazocarbonyl compounds Dong, Z.; Xiao, X.-Q.; Li, Z.; Lu, Q.; Lai, G.; Kira, M. Org. Biomol. Chem. 2015 6. 其他相关反应 6.5 α-羰基重氮阴离子和亲电试剂的其他反应 HBF-catalyzed formal cyclopropanation of EDA with α,β-unsaturated aldehydes Branstetter, B.; Hossain, M. M. Tetra