一种新型缓蚀剂对混凝土中钢筋的缓蚀作用-防腐工程有限公司.pdfVIP

一种新型缓蚀剂对混凝土中钢筋的缓蚀作用 何小松 1，雷俊 2 魏无际2 （1、东方建设（天津）防腐工程有限公司，天津 300222 2、南京工业大学 江苏南京 210000） [摘 要]利用线性极化法、失重法、极化曲线、电化学阻抗谱(EIS)等方法，研究了模 拟混凝土孔溶液中，一种新型缓蚀剂对钢筋的缓蚀作用和电化学腐蚀行为。结果表明，该缓 蚀剂对钢筋具有较好的缓蚀效果；最佳缓蚀剂浓度为 2%；该缓蚀剂能有效抑制氯离子对钢 筋的腐蚀并对混凝土力学性能无有害影响。其缓蚀作用主要是通过在钢筋表面的竞争吸附形 成保护膜从而提高钢筋耐腐蚀性。 [关键词] 缓蚀剂；钢筋；混凝土；极化曲线；电化学阻抗谱 Inhibition Effect of a new-type Inhibitor on the Steel Bar in Concrete 1 1 1 He xiaosong ,Lei Jun , Wei Wu-ji (1、 Orient(tianjin) Corrosion Engineering Ltd, TianJin,300222 China 2 、Nanjing University of Technology, Nanjing 210009, China;) Abstract: The inhibition effect and the electrochemical corrosion behavior of a new-type inhibitor on the steel bar in the NaCl-contented, simulated concrete pore solution were studied by linear polarization, weight loss, polarization curve and electrochemical impedance spectra (EIS). The results showed that the inhibitor had a good inhibition effect on the steel bar, and the optimum -P inhibitor concentration was 2%. The inhibitor can inhibit the corrosion of ClP on the steel effectively, and had no negative effect on the mechanical properties of the concrete. The mechanism is suggested that the protective film was formed on the steel bar surface through competitive adsorption. Key words: Inhibitor; Steel Bar; Concrete; Polarization Curve; Electrochemical Impedance Spectra. 1. 前言 混凝土中钢筋锈蚀会引起结构物破坏、造成重大经济损失，已成为世界性问 题。钢筋锈蚀的防护措施目前已有多种，如耐蚀钢筋、钢筋涂层、混凝土外涂层、 阴极保护、混凝土外加剂等。其中改进钢筋混凝土自身的防护能力被认为是最简 易且行之有效的方法,在混凝土中添加钢筋缓蚀剂就能起到这种作用。钢筋缓蚀 剂属于混凝土外加剂，使用方式分为内掺型和渗透型两类[1] 。 本文主要采用线性极化