Gemini型双阳离子表面活性剂的合成研究.pdfVIP

全国第十三次工业表面活性剂研究与开发会议 Gemini 型双阳离子表面活性剂的合成 杨建洲,苏秦岭,苗宗成,孙士伟 陕西科技大学化学与化工学院 陕西 咸阳 712081 摘要 以十二叔胺及其盐酸盐和环氧氯丙烷为原料 合成了Gemini 型双阳离子表面活性剂 讨论了各步反应的影响因素 得到合成十二烷基失水甘油基二甲基氯化铵 DGDMAC 的 最佳反应条件为 反应温度35 40 将十二叔胺 DTA 滴加入过量环氧氯丙烷 EPIC 中 n DTA n EPIC =1:5 滴加时间为 1h,保温搅拌4h 转化率95% Gemini 型双阳 离子表面活性剂的最佳反应条件为 将DGDMAC 0.19mol 以固体形式分多次加入含0.2mol 的DTAHC 的丙酮溶液中 1h 加完 反应温度40 50 总反应时间 6.5h 收率95% 并 通过元素分析 环氧值测定 羟值测定 阳离子测定 IR 谱等确认了DGDMAC 和Gemini 型双阳离子表面活性剂的结构 关键词 Gemini 双阳离子表面活性剂 十二叔胺 环氧氯丙烷 SYNTHESIS AND PROPERTIES OF NOVEL GEMINI CATIONIC SURFACTANTS YANG Jian-zhou, XU Liang MIAO Zong-cheng, SUN Shi-wei (College of Chemistry Chemical Engineering, Shaanxi University of science Technology. Xianyang 712081 China) Abstract : Using dodecyl tertiary amine(DTA), its hydrochloride (DTAHC) and epichlorohydrin EPIC as the material, gemini bis-cationic surfactant was synthesized in our laboratory. By discussing the influencing factor of each reaction, the best reactive condition of synthesizing DGDMAC was that the temperature of reaction was 35 40 , DTA was dripped into excessive EPIC and material mol ratio: n DTA n EPIC =1:5, dripping time was 1h and stirring time was 4h, and conversion rate was 95%. the best reactive condition of gemini bis-cationic surfactant was that DGDMAC 0.19mol with solid was dropped into acetone with 0.2mol DTAHC and the dropping time was 1h, and the temperature of reaction was 40 50 and the total reactive time was 6.5h, and yield was 95%. This structure of the product was characterized by the methods of IR, element analysis, epoxide determination, hydroxyl value determination, cation determination. Key words: gemini; bis-cationi