云南糯玉米龙须的化学成分研究.pdf

Journal of Organic Chemistry Research 有机化学研究, 2017, 5(4), 159-163 Published Online December 2017 in Hans. /journal/jocr /10.12677/jocr.2017.54021 Studies on Chemical Constituents from the Style of Zea mays Ling Zhang, Tiandong Zhang, Weiyao Hu, Baokun Zhu, Bo Cai, Qianxu Yang, Wei Zhao, Yinliang Zhao RD Center, China Tobacco Yunnan Industrial Co., Ltd, Kunming Yunnan st rd th Received: Nov. 21 , 2017; accepted: Dec. 3 , 2017; published: Dec. 11 , 2017 Abstract In order to discovery activity ingredients, the chemical component of style of Zea mays was stu- died. Chemical constituents of style of Zea mays were isolated by silica gel, sephadex LH-20, and Rp-18 column chromatography. And their structures were elucidated by spectral methods. Twelve compounds were isolated, and their structures were identified as 7-hydroxy-4’-methoxyisoflavone (1), chrysoeriol-6-C-α-boivinopyranosyl-7-O-β-glucopyranoside (2), stigmasta-4-en-3β, 6β-diol (3), 7α-hydroxysitosterol (4), daucosterol plamitate (5), 7α-hydroxysitosterol-3-O-β-D-glucopyranoside (6), palmitic acid (7), daucosterol (8), p-hydroxycinnamic acid (9), vanillic acid (10), soya-cere- broside I (11), β-sitosterol (12). Above all compounds were obtained from this plant for the first time. Keywords Zea mays, Chemical Constituents, Isolation, Identification 云南糯玉米龙须的化学成分研究 张 玲，张天栋，胡巍耀，朱保昆，蔡 波，杨干栩，赵 蔚，赵英良 云南中烟工业有限责任公司，云南 昆明 收稿日期：2017年11月21 日；录用日期：2017年12月3 日；发布日期：2017年12月11 日 摘 要 本论文研究了云南产的糯玉米的化学成分。采用正相硅胶、凝胶及反相材料进行化合物的分离和纯化， 文章引用: 张玲, 张天栋, 胡巍耀, 朱保昆, 蔡波, 杨干栩, 赵蔚, 赵英良. 云南糯玉米龙须的化学成分研究[J]. 有机 化学研究, 2017, 5(4): 159-163. DOI: 10.12677/jocr.2017.54021 张玲 等 采用IR、NMR、MS等现代波谱分析鉴定化合物的结构。结果：从云南产的糯玉米中分离得到个12化合