碳还原法分析硫酸盐的氧同位素组成-成矿作用与资源评价重点室.pdf

2011 8 30 4 August, 2011 MINERAL DEPOSITS Vol. 30 No. 4 : 0258-710 (2011) 04-0749-05 X 万德芳, 李延河, 秦 燕 ( , 100037) , , 3 , , , NBS- 127 S04- 1S04-2 , ? 01 2 j ( 1R) , ; ; ; ; + : P597 . 2 :A Carbon reduction method for oxygen isotope composition of sulfates WAN DeFang, LI YanHe and QIN Yan ( Key Laboratory of Isotope Geology of Ministry of Land and Resources, Institute of M ineral Resources, CAGS, Beijing 100037, China) Abstract T he oxygen isotopic composition and mass independent fractionation of sulfates can provide useful informa- tion for the formation conditions of sulfates, reveal special processes that cannot be acquired by element concen- tration or single isotope ratio measurements. This aspect is a frontier and hot topic in the isotope geochemical study both in China and abroad. The carbon-reduction method for oxygen isotope analysis of BaSO samples was 4 founded in the authors laboratory. The analytical processes of BaSO4 samples are described in this paper. T he oxygen isotope compositions of an international standard sample NBS- 127, laboratory work standard samples ( S04- 1) and laboratory w ork standard samples ( S04-2) were measured. This analytical method is simple and its operation is easy. The precision of oxygen isotope ratios of these samples is up to ? 012 j ( 1R) , better than 0115 j ~ 0129 j ( 1R) by W