气硬碱性酚醛树脂粘结剂促硬剂研究-毕业论文.docVIP

摘 要 树脂砂的应用引发了铸造生产工艺的一次革命。随着社会的发展，低污染甚至无污染的造型材料必将成为行业的主流。CO2硬化碱性酚醛树脂粘结剂作为绿色的铸造粘结剂，其较高的强度性能使其成为拥有宽广市场潜力和价值的造型材料。 本课题采用的树脂合成工艺为碱性法分段升温滴定合成工艺，将苯酚、甲醛、NaOH、邻苯二酚、对苯二酚、双份A以此工艺合成的树脂为基体树脂。 本文重点对交联剂的种类和加入量进行了系统深入的研究。在实验中，以抗压强度为主要考察目标，考察了碱、硅烷、硼砂、锡酸钠、铝酸钠加入量对芯砂抗压强度的影响，获得了最佳的加入量配比，制成了可用于生产的粘结剂。另外还对A剂的加入量进行了研究，实验表明A剂的引入极大的提高了芯砂的强度。 本文还对CO2硬化碱性酚醛树脂吹气工艺及其固化机理进行了分析研究，实验中得到了最佳的吹气时间和吹气流量。同时对CO2硬化碱性酚醛树脂粘结剂进行了工艺性能的测试，包括可使用时间，发气量，溃散性和树脂的加入量等，进一步证明了CO2硬化碱性酚醛树脂粘结剂性能的优越性。 从经济角度分析，对这种CO2硬化碱性酚醛树脂粘结剂与通用的三乙胺法硬化树脂粘结剂做比较，表明其作为新型铸造粘结剂具有明显的生产实用价值和经济效益。 关键词：酚醛树脂；冷芯盒工艺；交联剂 Abstract The application of resin sand triggered a revolution of the casting production process. With the development of society, non-polluting materials will become the mainstream of modeling industry. CO2-cured alkaline phenolic resin binder as a green binder foundry, its high strength properties make it have broad potential market and value of modeling materials. The resin process of this paper is sub-warming titration method synthesis. This process is basis resin for the synthesis of the resin matrix resin. This paper focuses on the type of cross-linking agent and the amount of system-depth study. In the experiment, the compression strength is the main factor in test. Inspected the joined amount of alkali, the silicon hydride, the borax, the sodiumstannate, the sodium aluminate to the coregranulated substance compressive strength influence，and obtained best joined quantity of allocated proportion, it has made the cementing agent which can be used in produce. Moreover, studied the amount of the A medicinal preparation , the experiment has indicated the A medicinal preparation can enormous enhance core granulatedsubstance intensity enormously. This article also analyse the research to the CO2 hardeningalkalinity phenolics air flush craft and its the solidificationmechanism. In the experiment , the best air flush time and the air flush current capacity has obtained. Meanwhile, carried on the shopcharacteristics test to the CO2