大功率材料毕业论文.docVIP

目录 中文摘要…………………………………………………………………………………1 英文摘要…………………………………………………………………………………2 1 绪论 3 1.1 压电材料和压电效应 3 1.2 压电陶瓷的结构 5 2.1.1 晶体结构 5 2.1.2 电畴 6 2.1.3 固溶体 6 1.3 掺杂改性 8 1.4 压电陶瓷的制备工艺对材料性能的影响 11 1.5 压电陶瓷的研究现状 13 1.5.1 研究进展 13 1.5.2 弛豫铁电体 14 1.5.3 几种PZT基陶瓷的特点 14 1.5.4 几种常见的化合物添加剂 16 1.6 研究背景和意义 16 2 实验部分 18 2.1 实验药品 18 2.2 样品制备 18 2.3 样品的表征方法 19 2.3.1 样品的密度测定 19 2.3.2 X射线衍射分析（XRD） 20 2.3.3 （SEM） 20 2.3.4 21 2.4 实验用主要仪器设备 22 3 结果与讨论 23 3.1 致密度分析 23 3.2 XRD分析 23 3.3 SEM分析 24 3.4介电、压电性能 25 结 论 29 谢 辞 30 [参考文献] 31 PZTMS基大功率压电陶瓷的制备与表征 摘 要:本文针对大功率压电陶瓷的性能要求，选取PZTMS陶瓷体系，采用传统固相法制备PZTMS基压电陶瓷运用X射线衍射、扫描电子显微分析等分析测试手段对陶瓷相结构、微观结构进行了表征；运用d33测试仪、阻抗分析仪等测量样品的压电、介电性能。 本文研究了Nb、Nd、Ce掺杂对P微观结构和性能的影响，分析了产生这些现象的原因，为对该体系掺杂改性的进一步研究提供了依据同时研究了烧结温度对P的压电、介电性能的影响。实验结果表明适量的Nb、Nd和Ce掺杂均能使压电陶瓷晶粒细化均匀和致密，提高性能。当Nb2O5含量为0.05wt.%，含量为0.2%，烧结温度为1200℃时，样品具有较好的综合性能ε /ε0=975、 Kp=0.61、Qm=663、d33=350pC/N，可以满足大功率器件的要求。 关键词: PZTMS压电陶瓷；掺杂；烧结温度；压电性能；介电性能  The preparation and characterization of PZTMS-based high power piezoelectric ceramics Abstract： the performance requirements of high-power piezoelectric ceramics, the PZTMS ceramics were studied in this paper. PZTMS+xwt.%Nb2O5+ywt.%Nd2O3+wmol%CeO2 ceramics were fabricated using the conventional ceramic techniques. The bulk densities of the sintered specimens were measured based on the Archimede’s method. The crystallite structure was examined using an X-ray diffraction(XRD) and the microstructure was observed using a scanning electron microscope(SEM). The piezoelectric and dielectric properties were measured by d33 meter and impedance analyzer etc. The effects of Nb, Nd and Ce doping on the structure and properties of PZTMS ceramics have been studied in this paper, as well as the reasons for these effects, which provide the foundations for further experiments. The effects of sintering temperature on the properties have also been studied. The results show that appropriate amount of Nb, Nd and Ce doping can improve the properties of piezoelectric ceramics by refining the gra