IIIStatisticDistributionsforidealgases教学教程幻灯片.pptVIP

2) In an isolated system, and in “平衡态” Thermodynamics: Statistical Physics: 极大时的熵S对应着热力学系统的平衡态。 极为自然的问题: ?和S 之间是否存在联系？ These arguments make it reasonable to postulate that with a degree of accuracy up to a constant multiplier thermodynamically defined entropy coincides(一致) with the quantity ?. 意 义 Boltzmann endue(赋予) the entropy an statistical meaning . 宏观的熵其微观含义如何？ It is convenient to use another definition form. Boltzmann consider this situation and thought that there must be some internal connection between them. He applied a multiple constant to establish an equation: ------The Bol