热处理对CaO_MgO_Al_2O_3_SiO_2系微晶玻璃组织及表面耐磨性的影.docxVIP

Vol.16 No.4Aug. 2011热处理对 CaO-MgO-Al2O3-SiO2 系微晶玻璃组织及表面耐磨性的影响樊 星 1，苏柳梅 1，胡 双 2，郑 峰 1(1. 中南大学 材料科学与工程学院，长沙 410083；2. 湖南省冶金材料研究所，长沙 410014)摘 要：对博德精工提供的商用 CaO-MgO-Al2O3-SiO2 系微晶玻璃－陶瓷复合板进行热处理。通过 DSC 分析确定热处理温度为 980 ℃(析晶峰值温度)。保温 10 min 时釉层中析出大量新微晶，结合 XRD 和 EDAX 分析结果，确 定新微晶相为长石、透辉石和硅酸锆。用扫描电镜(SEM)对样品表面进行形貌观察发现，经过 980 ℃/10 min 热处 理后，长石在不连续链状分布的氧化锆晶体周围成片状析出，透辉石主要在釉层表面析出，和长石一起在釉面形 成厚约 20 μm 的致密析晶层，使釉面的维氏显微硬度从热处理前的 6.5 GPa 提高到 7.5 GPa(提高 15%)，改善了釉 面的耐磨性能。升高热处理温度有利于提高釉面硬度；在 980 ℃下保温时间对釉面硬度的影响不大。 关键词：微晶玻璃；热处理；析晶；表面硬度中图分类号：TU56文献标识码：A文章编号：1673-0224(2011)4-498-07Effect of heat treatment on abrasion resistance andmicrostructure of glass-ceramics in CaO-MgO-Al2O3-SiO2 systemFAN Xing1, SU Liu-Mei1, HU Shuang2, ZHENG Feng1(1. School of Material Science and Engineering, Central South University, Changsha 410083, China;2. Institute of Material and Metallurgy, Changsha 410014, China)Abstract: In order to improve abrasion resistance, glass-ceramics in CaO-MgO-Al2O3-Si2O system supplied byGuangdong BODE Ltd. were evaluated by heat treatments. The effect of heat treatment on abrasion resistance and microstructure of glass-ceramics were studied. The results showed that a large quantity of new crystals precipitated upon heating at 980 ℃ for10 min according to DSC, XRD and SEM analysis. XRD and EDAX analysis showed that these newcrystals are consisted of feldspar, diopside and zirconium silicate. Mechanism of Precipitation of feldspar and diopside is different based on SEM images. Sheet-like feldspar was precipitated around original chain-like ZrO2 particles inside entire layer of glaze while diopside precipitated on the surface of glaze. Both of those was combined to form a rather tough and compact layer of 20 μm in thickness on the surface of glaze leading to Vickers microhardness increases from6.5 GPa to 7.5 GPa (equivalent to 15% higher in abrasion resistance). Increasing heat treatment temperature was beneficial to improve microhardness of glaze layer, while holding time had