Tertiary amine mediated aerobic oxidation of sulfides into…叔胺介导了硫化物有氧氧化成.pdfVIP

Chemical Science EDGE ARTICLE View Article Online View Journal | View Issue . Tertiary amine mediated aerobic oxidation of e c n e sulfides into sulfoxides by visible-light photoredox c i L Cite this: Chem. Sci., 2015, 6, 5000 9. d catalysis on TiO † e 2 4 t r : o 0 4 p : n a a a *a b 5 U Xianjun Lang, Wei Hao, Wan Ru Leow, Shuzhou Li, Jincai Zhao 1 6 0. and Xiaodong Chen*a 1 3 0 2 n / o 2 i t 0 u The selective oxidation of sulfides into sulfoxides receives much attention due to industrial and biological / b 4 i 2 r t applications. However, the realization of this reaction with molecular oxygen at room temperature, n t o A d s which is of importance towards green and sustainable chemistry, remains challenging. Herein, we e n d o a m develop a strategy to achieve the aerobic oxidation of sulfides into sulfoxides by exploring the synergy o l m n o between a tertiary amine and titanium di