化工外文文献翻译 用混合溶剂萃取精馏分离乙腈 乙酸乙酯 其他专业.docx

Separation of acetonitrile-ethyl acetate by extractive distillation with mixed solvent Li Chunli1, Zong Lili2 and Fang Jing School of Chemical Engineering, Hebei University of Technology, Tianjin, 30013 E-mail:lichunli_hebut@126.com, Tel: +86-022Abstract Computer-aided molecular design (CAMD) approach was bring in this work for selecting extractive solvents. The separation of acetonitrile-ethyl acetate Azeotropic system was carried out through a batch extractive distillation processes with N,N-dimethylformamide(DMF), glycol(EG) and DMF-EG mixture as solvents separately. The effects of different operating conditions were studied, solvents, ratio of mixed solvent, solvent flow rate and reflux ratio were all included. It was found that the mixed solvent DMF-EG showed better separation effect than the single solvent. The best proportion of the mixed solvent was 3:7 ( the quality of DMF and EG ); when the solvent flow rate and reflux ratio increased, the separation effect of mixed solvent improved; under the conditions that solvent flow rate was 20 mL/min, reflux ratio was 2, quality fraction of ethyl acetate in the top product could reach 99.62%. Keywords Separation; Batch extractive distillation; Mixed solvents; Acetonitrile; Ethyl acetate 1.Introduction Acetonitrile and ethyl acetate are widely used in chemical and pharmaceutical industries as chemical raw materials and good organic solvent[1]. But the two form azeotrope, ethyl acetate hold 77% and the other 23% is acetonitrile(mass fraction), common distillation method can not make any effect. Therefore, some companies have to treat them as waste, this not only cause seriously waste of resources and economy, but also pollute the environment. At present, Di Jiandong[2]of Tianjin university has realized the separation of acetonitrile-ethyl acetate by heterogeneous batch azeotropic distillation, but the product received in this way have lower purity, but high energy consumption. According to the difference of