大学化学第二章化学热力学初步教材教学课件.pptVIP

计算 (4) 2C (石墨) + 2H2(g) + O2(g) = CH3COOH(l) = ? △rHm(4) 已知：(1) CH3COOH(l)+2O2(g)=2CO2(g) + 2H2O(l) = - 870.3kJ.mol-1 (2) C(石墨) + O2(g) = CO2(g) = - 393..5kJ.mol-1 (3) H2(g) + 1/2 O2(g) = H2O(l) = - 285.5kJ.mol-1 △rHm(1) △rHm(2) △rHm(3) △rHm(1) △rHm(2) △rHm(3) △rHm(4) ∴ = ×2 + × 2 - =(-393.5)×2 + (-285.5)×2 -(-870.3)