原创力文档Diagnostic Characterization of Battery Electrodes, Frank McLarnon, Lawrence Berkeley National Lab推荐.pdf
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Diagnostic Characterization of Battery Electrodes, Frank McLarnon, Lawrence Berkeley National Lab推荐
DIAGNOSTIC CHARACTERIZATION
OF BATTERY ELECTRODES
presented by
Frank McLarnon
Lawrence Berkeley National Laboratory
Berkeley, California 94720
US – China Electric Vehicle and Battery Technology Workshop
August 31, 2010
Li-Sn Reference Electrode Cell Measurements
1
• Measurements in cells with Li-Sn reference FULL 3
electrodes help quantify contributions of 4 2
positive and negative electrodes to cell
impedance and impedance rise during cycling
and aging
• Full cell data show that electrolyte salt has a
significant effect on cell impedance: 2 1
m NEG
LiBOB LiBF LiF OB LiPF c 3
4 2 6 -
Ω 4 2
,
• The negative electrode is more affected by )
m
I
(
electrolyte salt than the positive electrode Z-
• Other data indicate that the electrolyte salt has
a strong influence of SEI properties
POS
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