环境催化技术2.pptVIP

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环境催化技术2.ppt

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环境催化技术2

Background Coal-fired boilers: generation of many air pollutants SO2 and NOX in Flue gas: main air pollutants in China Flue gas treatment: high pollutant removal rate, independent of boiler type and fuel type Current technique: single pollutant removal, high cost Dry and catalytic methods: - capable for multi-pollutants removal - suitable for sulfur recovery - save H2O De-SO2 De-NOX De-VOC De-TM De- ？ Dry and Catalytic Process for Simultaneous Removal Two mode operation in each cycle Flue gas (SO2, NOX) Cleaned flue gas Solid ammonium sulfate NH3 NH3 SO2 NOX removal Regeneration S-recovery Adsorption of SO2 reduction of NO to N2 Requirements to the Catalyst Active at flue gas temperatures High capacity for SO2 adsorption high activity for NOX reduction to N2 Same temperature regeneration Temperature of most flue gas at stack: ? 200?C Activated carbon: active for simultaneous SO2 and NO removal at ? 200?C Honeycomb catalyst: avoids particulate plugging ACH Catalysts and experimental conditions Coal-derived activated carbon Honeycomb Subjected to thermal treatment at 850?C (ACH) Supporting of V2O5 (2 wt%) by impregnation of NH4VO3 V2O5/ACH1 V2O5/ACH2 Fixed bed reactor: 200?C, 1850 h-1; 1520 ppm SO2, 450 ppm NO, 500ppm NH3, 2.5% H2O, 3.8% O2, Ar Regeneration: 5%NH3/Ar, 330?C, 1 h With different AC and binder Physical Properties of the ACH supports Binder and processing affects the properties of the ACH The AC has more micro-pores than ACH2 ACH1 and ACH2 have similar micro-pore structure Samples Proximate analysis Ultimate analysis SBET/m2.g-1 M A V C H O N ACH1 1.8 42.1 8.2 50.1 3.2 2.1 0.43 532 ACH2 1.0 34.5 5.2 58.7 2.3 2.7 0.43 619 Granular AC 2.9 10.3 10.8 77.3 2.0 6.0 1.20 936 ACH2 was made from the granular AC Main difference : inorganic material (binder) surface area Properties of the ACH supports (wt%) Effect of support on simultaneous SO2 and NO removal SO2 removal NO removal fresh fresh regene