二次有机气溶胶估算方法研究进展.PDFVIP

中国环境科学 2014,34(3) ：555~564 China Environmental Science 二次有机气溶胶估算方法研究进展 郑 玫,闫才青,李小滢,王雪松,张远航* (北京大学环境科学与工程学院,环境模拟与污染控制国家重点联合实 验室,北京 100871) 摘要：我国区域复合污染日趋严重,二次有机气溶胶(SOA)是细颗粒物 PM2.5 的重要组成之一.本研究总结了当前国内外定量估算 SOA 的主 要方法,包括 EC 示踪法、WSOC 法、受体模型法、示踪物产率法、数值模拟法等.通过对各种方法的原理介绍与比较,指出 1)EC 示踪法、 WSOC 法、受体模型法简单易行,与在线连续观测数据结合可估算高时间分辨率的 SOA 浓度,但受限于对当地源谱和特定物种的了解;2) 示踪物产率法虽分析技术难度高,但可针对不同来源的 SOA 估算;3)数值模拟可获得大尺度 SOA 的空间分布.针对国内外的最新研究成果 进行简单概述,不同方法的研究表明中国二次有机气溶胶是总有机气溶胶的重要部分,人为源 VOCs 对二次有机气溶胶发挥着重要贡献. 文旨在为未来我国二次有机气溶胶的研究提供基础信息和研究思路. 关键词：二次有机气溶胶；细颗粒物；定量估算方法；来源；中国 中图分类号：X513 文献标识码：A 文章编号：1000-6923(2014)03-0555-10 A review of methods for quantifying secondary organic aerosol. ZHENG Mei, YAN Cai-qing, LI Xiao-ying, WANG * Xue-song, ZHANG Yuan-hang (State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China). China Environmental Science, 2014,34(3) ：555~564 Abstract ：Regional air pollution is complex and becomes increasingly important in China. Among many others, secondary organic aerosol (SOA) is one of the most important components of PM2.5 . This paper discusses various methods for quantifying SOA in the atmosphere (including methods based on the EC tracer, WSOC, receptor model, the SOA tracers, and air quality model), presents the basic principle of each method and points out that 1) the EC-tracer method, the WSOC method and the receptor model method are relatively simple and convenient, but limited by the availability of local source profiles and some specific tracers; 2) the SOA-tracer method is analytically challenging but can supply source-specific SOA information; and 3) the air quality model method can provide larg