同位镀铋方波溶出伏安法检测蜂蜜中的痕量铅-食品安全质量检测学报.PDFVIP

3 5 Vol. 3 No. 5 2012 10 Journal of Food Safety and Quality Oct. , 2012 * 吴小娟, 蔡健荣 , 韩 恩, 周立娜, 陈铭枫 (, 212013) 摘 要: 目的 方法 ,,结果 , pH, , , −0.580 V, 5~100 μg/L(r=0.9965), 0.630 μg/L 结论 关键词: ; ; ; ; Determination of trace lead in honey with in-situ bismuth film electrode by square wave stripping voltammetry WU Xiao-Juan, CAI Jian-Rong * , HAN En, ZHOU Li-Na, CHEN Ming-Feng (School of Food and Biological Engineering, Jiangsu University , Zhenjiang 212013, China) ABSTRACT: Objective To determine the trace lead in honey with in-situ bismuth film electrode by square wave stripping voltammetry. Methods Using glassycarbon electrode in-situ plated in bismuth (III), replacing in traditional mercury(II), the trace lead in honey was rapidly detected by square wave stripping voltammetry 3+ method. Results Several factors were optimized, including buffer solutions, pH, the concentration of Bi , plating potential and plating time. Sensitive stripping peak of lead was obtained at the potential of -0.580 V in the bismuth film electrode. Under the optimized analytical condition, the stripping peak currents were changed linearly with the concentration of Pb2+ over range from 5 ~100 μg/L (r=0.9965) with a detection limit of 0.630 μg/L. The result was in accordance with that of graphite furnace atomic absorption spectrometry (GFAAS). Conclusion The established method is rapid and accurate in detecting trace lead in honey. KEY WORDS: electrochemistry; in-situ plating bismuth film; strippin