南方冶金学院硕士学位论文开题报告格式要求-有色金属科学与工程.DOCVIP

微波改性麦糟处理低浓度含砷水试验研究 丁丽超陈云嫩（江西理工大学资源与环境工程学院，江西赣州341000） 摘 要：金属废水排放造成资源浪费，已成为饮用水源最大的安全隐患之一其治理一直是世界环保领域的重大课题。为了顺应我国新的《生活饮用水卫生标准》(GB5749-200)，即将《生活饮用水卫生标准》(GB5749-) 中砷标准从0.05 mg/L降低到0.01 mg/L本选择废麦糟作为工业废水中具有代表性的阴离子砷(Ⅲ)，采用微波改性麦糟作为吸附剂，对低浓度含砷水进行试验研究。确定最佳改性条件为低火强度下改性7 min。在pH为9，微波改性麦糟投加量10 g/L条件下，初始浓度为0.5 mg/L 的含砷水可在35 min达到吸附平衡，最高去除率达到99.4%。微波改性麦糟对砷的吸附动力学行为符合准二级方程。 关键词：麦糟；生物吸附；微波改性；含砷水 Study on the treatment of water containing low arsenic strength using spent grains modified by microwave Ding lichao, Chen yunnen*, Chai liyuan (School of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou,341000, China) Abstract: Not only the outlet of wastewater containing heavy metals wastes lots of resourses, but influences the safety of drinking water. So the treatment of the wastewater has always been an important project in the world environmental protection. In order to conform the new Standards for Drinking Water Quality (GB5749-2006), in which the concentration of arsenic has fallen from 0.05 mg/L in Standards for Drinking Water Quality (GB5749-85) to 0.01 mg/L, spent grains was chosen as raw material for adsorbent, arsenic (Ⅲ) being a representational anion in industrial wastewater as treating object. Using spent grains modified by microwave as biosorbent, the treatment of water containing arsenic was studied. The optimal modified conditions of spent grains were low-fire microwave 7 min. Experimental results showed that when pH 9, modified spent grains 10 g/L, initial arsenic concentration 0.5 mg/L, biosorption reaction 30 min, arsenic removal rate can reach 99.4 %. The kinetics sorption model of modified spent grains to arsenic accorded with quasi-second kinetics equation. Key words: spent grains; biosorption; microwave modification; water containing arsenic; kinetics 1 前言 砷是一种有毒元素，它可以通过食物、饮水或皮肤接触进入人体，在肝、肾、骨骼、毛发等器官或组织内蓄积，从而引起砷中毒。在地下水中的存在形式有H2AsO4-、HAsO42-、H3AsO3和H2AsO3-。砷的毒性与它的形态有关，其中三价砷的毒性比五价砷和砷高 [13]。目前含砷废水的处理方法主要有[4-8]：沉淀法、离子 生物吸