污水污泥间壁热干燥实验研究.pdf

第 28 卷第 2 期 环 　　境 　　科 　　学 Vol. 28 ,No. 2 2007 年 2 月 ENVIRONMENTAL SCIENCE Feb. ,2007 污水污泥间壁热干燥实验研究 王兴润 ,金宜英 ,王志玉 ,杜欣 ,聂永丰 (清华大学环境科学与工程系 ,北京 　100084) 摘要 :研究了污泥间壁热干燥的工艺过程 ,分析了其工艺参数、冷凝水水质和产生的污染气体 ,探讨了有机物水解机理. 结果 ( ) 表明 ,污泥含水率与停留时间呈负指数函数相关. 收集到的干燥冷凝水属高浓度有机废水 ,其总有机碳 TOC 、挥发性有机酸 ( ) ( N) 浓度均很高 ,pH 值保持在 9～95. 干燥冷凝水中挥发性有机酸和氨氮来源于 2 部分 :低温 110 ～130 ℃ VFA 和氨氮 NH3 时 ,主要发生蛋白质的水解 ,生成有机酸和氨氮 ;高温 140～150 ℃时 ,主要发生脂肪类的水解 ,生成有机酸. 干燥温度低于 150 ℃时 ,污泥间壁热干燥过程无污染气体产生. 关键词 :间壁热干燥;干燥冷凝水 ;水质分析 ;有机物水解机理 ( ) 中图分类号:X705 　文献标识码 :A 　文章编号 2007 Experimental Research on Indirect Thermal Drying Process of Se wage Sludge WANG Xingrun , J IN Yiying , WANG Zhiyu , DU Xin , NIE Yongfeng ( ) Department of Environmental Science and Engineering , Tsinghua University , Beijing 100084 , China Abstract :Technical parameter , condensed steam water quality and flue gases were studied and organic compound hydrolysis mechanism was discussed. During experimental study , observed that the relationship between water content of sewage sludge and residence time have a negative exponential function. The condensed steam water has a highconcentration organic content. Total organic carbon ( TOC) , volatile fatty acid (VFA) and NH N of the water were very high and the pH value was between 9 and 95. VFA and NH N come from two sections : ①In the 3 3 110～130 ℃temperature range , hydrolysis of protein occurred with the