固定床中好氧颗粒污泥动态吸附结晶紫染料.pdfVIP

中国环境科学 2015,35(6) ：1726~1733 China Environmental Science 固定床中好氧颗粒污泥动态吸附结晶紫染料 * 张彦灼,李文静,李 军 ,卞 伟,李 芸,陈光辉 (北京工业大学建筑工程学院,北京市水质科学与水环境恢复 工程北京市重点试验室,北京 100124) 摘要：针对印染废水色度高,脱色难度大的问题,通过固定床工艺利用灭活的好氧颗粒污泥(AGS)对水中结晶紫(CV)进行动态吸附.通过对 固定床高度、CV 初始浓度和和流速对穿透曲线的影响进行探讨,采用 Thomas 模型和 BDST 模型对动态吸附试验所得数据拟合并获得了 相应参数.试验结果表明,随着固定床高度的增加,穿透时间和饱和吸附时间延长;当 CV 初始浓度和流速增加时,穿透时间和饱和吸附时间急 剧缩短.Thomas 模型能够很好地描述 AGS 对 CV 的动态吸附动力学.当 CV 浓度为 100mg/L,流速为 8.3mL/min,固定床高度为 20cm 时 AGS 对 CV 的吸附动力学与 Thomas 模型拟合程度最好,相关系数为 0.9813.BDST 模型能准确预测穿透时间,平均误差小于 10%.吸附 CV 染料后 AGS 可用无水乙醇进行再生. 关键词：好氧颗粒污泥；结晶紫；动态吸附；固定床；BDST 模型；Thomas 模型 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2015)06-1726-06 Fixed bed column study for the adsorption of crystal violet dye by aerobic granular sludge. ZHANG Yan-zhuo, LI * Wen-jing, LI Jun , BIAN Wei, LI Yun, CHEN Guang-hui (Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, College of Architecture and Civil Engineering, Beijing University of Technology, Beijing 100124, China). China Environmental Science, 2015,35(6)：1726~1733 Abstract ：The high colority and hard to decolorization were the most important tasks on printing and dyeing waste water. The ability of inactivated aerobic granular sludge (AGS) to adsorb crystal violet (CV) from aqueous solutions using fixed bed column reactor were studied. Column adsorption studies were carried out at different bed heights, initial dye concentrations and flow rate. Column adsorption experimental data and corresponding parameters were obtained by Thomas model and bed depth service time (BDST) model. Results showed that as the height of adsorbent was increasing, breakthrough time and adsorption saturation time became longer. But when the initial dye concentrations and flow rate were increasing, breakthrou