空气污染物及其光化反应生成臭氧浓度之日变化分析-水土保持学系.PDF

空氣污染物及其光化反應生成臭氧濃度之日變化分析 陳鴻烈 (1) 羅惠芬 (2) 摘 要 本研究是採用苗栗縣境內環保署三義測站之數據，利用電腦EXCEL 的運算方式，統計出 各指標污染物之日變化情形，再將結果分為季節變化加以討論，並加入環境因子進行分析。本 研究採用的指標污染物包括臭氧、一氧化氮、二氧化氮，及氮氧化物等測值。結果顯示：(1) 臭 氧的變化情形受到氮氧化物的影響甚大，而當時的氣候條件 (溫度、日照) 亦產生影響；(2) 夏 天因為溫度及日照的關係，使得臭氧濃度有較高的趨勢；(3) 臭氧濃度之日平均變化與日照量 之日平均變化一致，由此可知，臭氧之變化情形受到日照的影響很大；(4) 臭氧的形成機制複 雜，希望能加入空間分析做進一步的研究。 關鍵詞( ：臭氧、日變化、三義測站) Diurnal Changes of Primary Air Pollutants and Secondary Former Ozone Paris Honglay Chen Professor, Department of Soil and Water Conservation, National Chung Hsing University, Taichung, Taiwan 402, R.O.C. Hui Fen Lo Graduate Student, Department of Soil and Water Conservation, National Chung Hsing University, Taichung, Taiwan 402, R.O.C. ABSTRACT This study applied the data from San-I monitoring station of Environmental Protection Administration (EPA) in Miaoli county to calculate the diurnal changes of every pollution index by EXCEL method. The results obtained were adjusted to seasonal variations again. Simultaneously, the environmental factors were also added to discuss their influences. The indicator pollutants of this study included O , NO, NO , NO , etc. The results showed (1) ozone variations were strongly 3 2 x influenced by NOx, and weather conditions about temperature and sunshine also caused influences; (2) (1)國立中興大學水土保持學系教授 (2)國立中興大學水土保持學系研究生 1 水土保持學報 41(1) ：1-16 (2009) Journal of Soil and Water Conservation, 41(1) ：1-16 (2009) ozone concentrations had higher trend in summer because of temperature and sunshine;