agpb10late12热电合金的液相合成及电学性能分析 word格式.docxVIP

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agpb10late12热电合金的液相合成及电学性能分析 word格式.docx

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agpb10late12热电合金的液相合成及电学性能分析 word格式

AbstractAgPbmLaTem+2thermoelectricalloyhashighelectricalconductivity,however，thedimensionlessfigureofmeritofbulkAgPbmLaTem+2materialsislowduetothehigh thermal conductivity.Recently, literaturereportssuggests that low-dimensionalandnanoscalematerialscaneffectivelyscatterphonons,therebysignificantlyreducingthethermalconductivity.Ontheotherhand,theenergyfilteringeffectof grainboundaries whichlow-energy carrierscannot passthrough canlargely increaseSeebeckcoefficients.Meanwhilethenegativeimpactofelectricalconductivitycanbeoffset,leadingtotheimprovementofthermoelectricperformance.Therefore,controlledsynthesisoflow-dimensionnanothermoelectricalloys,measurementof electricalproperties,anddiscussionoftherelationshipbetweenmorphologiesandpropertiescanprovideatheoreticalandexperimentalbasistoenhancethermoelectricproperties.Here,micro-/nano-meterAgPb10LaTe12thermoelectricalloyswithdifferentsizesandmorphologiesweresynthesizedcontrollably usinghydro/solvothermal. XRD,FESEM,HRTEM,andXPSwereemployedtocharacterizethestructures, morphologies,phasecompositionsandsurfacecompositionsofAgPb10LaTe12thermoelectricalloys,respectively.Cubes,flower-likesampleswitheightpetalsand rodswereobtainedbyadjustingsolvents,surfactants,andKOHconcentrations.Accordingtotimedependentexperimentalresults,thepossibleformationmechanismofvariousshapesobtainedunderdifferentconditionswasdiscussed. Theelectricalpropertiesofsampleswithdifferentmorphologiesweremeasuredand therelationshipbetweenmorphologiesandelectricalpropertieswasdiscussed.Theresultsindicatethattheelectricalconductivityofrod-likesampleisthehighest,Seebeck coefficient ismoderate andthe powerfactoris highest.Basedontheaboveexperimentalresults,pearlnecklace-likeAgPb10LaTe12microrodswereobtainedusingcitricacidassurfactants,waterassolvents,andwas characterizedbyXRDandSEMtechniques.OnthebasisofSEMimagesofsamplespreparedatdifferenttimes,theformationmechanismofthepearlnecklace-likemicrorodssampleswasproposedtheorientedattachmentmechanism.Byadjustingtheexp