基于表面起皱平面与球面图案化-patterning based on surface lift surface and spherical surface.docx

优秀毕业论文 精品参考文献资料 ABSTRACT It is well known that surface topographies play an important role in material properties. In recent years, fabrication of regular micropatterns on material surface has attracted lots of interest. Among various surface patterning methods, Surface wrinkling, as a novel and simple method to create ordered surface wrinkle morphologies, has become one of research focuses. In this thesis, fabrication of ordered micropatterns on material surface has been explored based on the surface wrinkling mechanism. According to the geometry of the wrinkled surfaces, the thesis is divided into two parts – wrinkling on planar surface and wrinkling on spherical surface. In the first part, ordered hierarchical stress-relief wrinkles with well-defined microstructures have been fabricated via a template-guided surface wrinkling. The novel stable structured template is the highly oriented sinusoidal wrinkle with the tunable wavelength and amplitude, which is produced by oxygen plasma (OP) treatment of a uniaxially strained polydimethylsiloxane (PDMS) sheet followed by strain release. When the wrinkled template is conformally contacted with a polystyrene (PS) film that is coated on the compliant PDMS foundation under heating, the confinement-induced wrinkling from the template takes place on the PS–PDMS substrate. The resulting aligned wrinkles with a style A mode and style M mode are controlled by the ratio of the applied template wavelength to the film intrinsic wrinkling wavelength, regardless of the geometric feature of the underlying substrate in our case. When the template-directed wrinkling is carried out two times on the same PS-PDMS substrate, inaccessible hierarchical complex wrinkles from the well-organized A-A, M-M and A-M are obtained by means of the smart combination of the same or different wavelengths of wrinkled templates. The involved unprecedented template-induced wrinkling on the as-formed wrinkles has been discussed briefly. During the whole pat