超声辅助处理回收锂离子电池正极材料_郭雅峰.pdfVIP

第26 卷 第5 期 电 子 元 件 与 材 料 Vol.26 No.5 2007 年5 月 ELECTRONIC COMPONENTS AND MATERIALS May 2007 超声辅助处理回收锂离子电池正极材料 郭雅峰，夏志东，毛倩瑾，丁 涛 摘要: 20 min60 min 100 mL DMAc 14.6 g 78 % 关键词: 中图分类号: X78 文献标识码:A 文章编号:1001-2028（2007）05-0036-03 Recovery of cathode materials from lithium-ion batteries with auxiliary ultrasonic method GUO Ya-feng, XIA Zhi-dong, MAO Qian-jin, DING Tao (College of Materials Science and Engineering, Beijing University of Technology, Beijing 100022, China) Abstract: Ultrasonic auxiliary separation was applied in the recycling process of cathode materials from lithium-ion batteries. With appropriate organic solvent, ultrasonic treatment time and holding time, it was possible to separate coating from Aluminum foil. This approach could be directly used to recycle Aluminum foil. The separated black powder (LiCoO2) of coating can be used as raw materials for synthesizing cobalt chemical product as well. When ultrasonic treatment time was not less than 20 min and holding time was not less than 60 min, cathode materials of 14.6 g was able to be segregated by using 100 mL DMAc organic solvent. The used organic solvent was recovered and reused through distilling process, with its recovery 78 % approximately. Key words: environmentalology; lithium-ion battery; ultrasonic treatment; cathode materials; recovery 锂离子电池由外壳和内部电芯组成，外壳为不锈 因此，如果能把铝箔与正极涂层有效分离开，就 钢或塑料，电池的内部电芯为卷式结构，主要由正极、 能够提高正极材料的回收率，减少强酸、强碱的使用。 负极、隔膜和电解液组成。其中，正极材料包括约90 % 笔者尝试在超声辅助的作用下，选择不同的强极性溶 （质量分数，下同）钴酸锂活性物质、7 %~8 %