环境科学、化学专业毕业论文：乳状液膜法处理苯胺废水的实验室研究（可编辑）.docVIP

环境科学、化学专业毕业论文：乳状液膜法处理苯胺废水的实验室研究 4 2.4实验原理……………………………………………………………………………4 2.5实验方法………………………………………………………………………..4 2.5.1最大波长的选择…………………………………………………………………5 2.5.2绘制标准曲线………………………………………………………………….5 3乳状液膜法处理苯胺废水……………………………………………………………6 3.1试剂与仪器…………………………………………………………………………6 3.2实验原理……………………………………………………………………………7 3.3实验方法……………………………………………………………………………7 3.3.1液膜的制备…………………………………………………………………….7 3.3.2富集分离……………………………………………………………………….7 3.3.3测定…………………………………………………………………………….7 3.4工艺条件的选择……………………………………………………………………7 3.4.1表面活性剂用量的影响……………………………………………………….7 3.4.2乳水比的影响………………………………………………………………….8 3.4.3油内比的影响…………………………………………………………………9 3.4.4外水相pH值的影响……………………………………………………………..10 3.4.5膜增强剂液体石蜡用量的影响…………………………………………………11 3.4.6条件验证实验………………………………………………………………….12 4结论……………………………………………………………………………………12 致谢………………………………………………………………………………………..13 参考文献…………………………………………………………………………………….14 乳状液膜法处理苯胺废水 的实验室研究 摘要 研究了苯胺水溶液的乳化液膜煤油-磷酸三丁脂-Span-80-HCl溶液处理过程,对溶剂和表面活性剂的选择及用量、膜增强剂用量、搅拌速度、乳水比 Rew、油内比 Roi、外相pH值及处理时间的影响进行一系列的研究。结果表明,在适宜的操作条件下,当水中苯胺浓度为510.8 mg/L时,经过一级液膜处理,水中苯胺的含量可降到1.405 mg/L,苯胺去除率可达99%以上,可以达到国家二级排放标准。 关键词:乳化液膜; 分离富集; 苯胺 Emulsion liquid membrane treatment of wastewater containing aniline laboratory studies Abstract: The ext raction of aniline f rom aqueous solution was performed by emulsion liquid membranekerosene-tribytyl phosphate TBP-Span-80-HCl aqueous solution process. The selection of parameters including dissolvant and surfactant , stirring speed , Roi , Rew , and pH of the external phase was also studied. The experiment showed that , under suitable conditions , the concent ration of aniline was less than 1.405 mg/L in the external aqueous phase t reated by one stage liquid membrane process when the initial concent ration of aniline was 510.8 mg/L in aqueous solution. aniline was up 99%. Keywords: emulsion liquid membrane; Separation enrichment; Aniline 1引言 1.1乳状液膜法在废水处理中的应用 液膜分离技术是1968年美国埃克森研究工程公司的黎念之博士首先提出并申请专利的一种新型膜分离方法[1],此技术具有膜薄1-10μm、比表面积大、分离效率高