sas法合成mnoxfeoy复合氧化物低温nh3scr催化剂的研究-study on synthesis of low temperature n _ h3 scr catalyst of mnoxfeoy composite oxide by sas method.docxVIP
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sas法合成mnoxfeoy复合氧化物低温nh3scr催化剂的研究-study on synthesis of low temperature n _ h3 scr catalyst of mnoxfeoy composite oxide by sas method
temperaturerangebetween180°Cand260°C,thelargestNOconversionat220℃couldreach97%,andthebiggestN2selectivityisalmost100%.KeyWords:DeNOxprocess,Selectivecatalyticreduction(SCR),ComposedoxideMnOx-FeOy,SupercriticalFluid(SCF)目录第一章文献综述...................................................................................................11.1NOx的危害及其现状11.1.1NOx的性质及其产生机理11.1.2NOx的主要来源31.1.3我国NOx的排放现状3NOx的危害4NOx的控制技术61.2NH3-SCR的原理及工艺流程71.3低温NH3-SCR催化剂的发展91.3.1分子筛催化剂..............................................................................91.3.2碳基材料催化剂.........................................................................101.3.3负载型金属氧化物催化剂.........................................................111.3.4贵金属催化剂.............................................................................121.3.5非负载型金属氧化催化剂.........................................................131.4超临界流体微粒化技术........................................................................141.4.1超临界抗溶剂技术(SAS)的原理151.4.2超临界抗溶剂技术的应用.........................................................161.5本课题的研究思路与内容....................................................................17第二章催化剂制备及表征方法.........................................................................192.1实验原料................................................................................................192.2实验装置................................................................................................202.3催化剂的制备........................................................................................202.3.1SAS法制备锰铁复合氧化物前驱体202.3.2共沉淀法制备催化剂前驱体.....................................................222.3.3焙烧.............................................................................................222.4催化剂的表征........................................................................................222.4.1高分辨透射电镜(HRTEM)222.4.2热重分析(TGA)222.4.3N2的吸附脱附232.4.4原子发射光谱分析方法(ICP)232.4.5X-射线衍射(XRD)232.5.1配气系统.............................................................................
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