不同活化方法对开心果壳活性炭地孔结构影响.docVIP

不同活化方法对开心果壳活性炭的孔结构影响 陈虹霖1，宋 磊2 （1，2华侨大学化工学院，福建 厦门 361021） 摘 要：本文以开心果壳为原料，探讨ZnCl2法、ZnCl2-KCl-H2O联合活化法对活性炭孔结构的影响。研究表明，ZnCl2法制备的开心果果壳活性炭以微孔为主，40 %ZnCl2溶液浸渍、在500 ℃下活化1.5 h得到的活性炭的比表面积为630 m/g；对于ZnCl2活化法和KCl活化法，活化都能增强活化效果，尤其对KCl活化的增强效果明显ZnCl2-KCl-H2O联合活化法能有效中孔，40 %ZnCl2和6 %KCl900 ℃下活化1.5 h得到的活性炭的中孔添加量为0.10 cm3/g，比表面为740 m2/g，中孔孔径集中在4 nm 关键词：开心果壳；活性炭；孔结构X705 文献标识码：A 文章编码： The Effect of Different Activation Methods on The Pore Structure of Activated Carbons Prepared from Pistachio Shells CHEN Hong-lin1, SONG Lei2 (1,2School of Chemical Engineering, Huaqiao University, Xiamen 361021, China) Abstract: Activated carbons was prepared from Pistachio nut shells by using ZnCl2, KCl and ZnCl2-KCl-H2O as activated agents， and were tested at －℃ to obtain the N2 adsorption isotherms to get the pore and surface properties. It showed that the pore structure of ZnCl2-activated carbons was main micropore, and the max BET area of the activated carbons was 630 m2/g. Using KCl as activeated agent, the BET area was only 70 m2/g. The activation effect was improved by introducing vapor as the activation gas by using ZnCl2 and KCl as activated agent. Addition H2O as the activation gas played a much more important role on addition new pore, especially for the method of KCl, and it’s BET area increased by about 9 times, and the pore structure was main micropore. Mesopore was effectivlely donated by using ZnCl2-KCl-H2O as mixed activated agents. Under the condition of impregnating with 40 %ZnCl2 and 6 %KCl, the BET area of the activated carbons was 740 m2/g for 1.5 hours activated time on 900 ℃, and the mesoporous volume was 0.10 cm3/g, and the major pore size of mesopores was about 4 nm. Key words: pistachio nut shell; activated carbon; pore structure；mesopore addition 活性炭( activated carbon，简称 AC) 是一种孔隙结构发达的多孔性功能炭材料。近年有诸多采用油茶壳[1]、城市固体有机废弃物[2]、烟草杆[3]、枣椰子树根[4]、竹质[5]、椰壳[6, 7]制备中孔活性炭的研究。用廉价的农产品废弃物制备高性能的活性炭研究的热点。开心果壳是我国近几年出现的农产品废弃物，国外已有对开心果果壳制备活性炭的研究[8-13]，但只局限于高比表微孔活性炭的制备，对于如何控制结构特别是中孔结构。此