20万吨固定FCC轻汽油醚化装置设计.docx

20万吨∕年固定床FCC轻汽油醚化装置设计摘 要本文主要通过对国内外催化轻汽油醚化的各种工艺技术的研究，总结出FCC汽油经过醚化反应，汽油轻馏分中的活性烯转化为醚，可使辛烷值提高2～3个单位。由于FCC汽油轻馏分中烯烃约占总汽油中烯烃的90％，因此将活性烯转化为醚后，烯烃的质量分数减少约23％，改善安定性。辛烷值的提高也减少了体系调和高辛烷值汽油对重整汽油的需要量，从而降低了汽油中芳烃的质量分数，并增加汽油的氧含量，是提高催化汽油质量的有效途径之一。以国内几家催化裂化轻汽油醚化工艺技术和国外几家催化裂化汽油醚化工艺技术为研究对象，分析了各种工艺技术的流程及工艺特点。重点研究了催化轻汽油的选择加氢技术和醚化反应技术，并详细计算了20万吨/年催化裂化汽油的醚化装置设计的过程。重点研究了催化轻汽油的选择加氢、醚化反应和异构化技术，通过分析论证，总结出最佳的催化裂化轻汽油醚化工艺流程。从工程设计方面重点探讨催化裂化汽油轻馏分醚化工艺中流程和设备选型方面的问题。主要包括分馏塔、加氢反应器、醚化反应器的装置设计。本设计采用固定床及两台反应器串联的工艺流程，过程简单，操作平稳，投资少，可大大改善了催化裂化汽油的质量。关键词:催化裂化轻汽油；醚化；装置设计；工艺流程AbstractThrough the domestic and international catalytic light gasoline etherification of all kinds of technology research, summarizes the FCC paper FCC gasoline light distillates etherification change is to improve the quality of gasoline, meets the requirements of environmental protection ideal process. The FCC gasoline light fractions of the active ene into the ether, can make octane Numbers increased by 2 to 3 unit. Due to the FCC gasoline light olefins in the fraction of total gasoline olefins 90%, will therefore propylene activity into the ether, olefins quality score 23% reduction, improve the stability. The improvement of octane rating also reduce high octane value to attune to reforming the gasoline demand, so as to reduce the mass fraction of aromatics in gasoline.On the choice of catalytic light gasoline hydrogenation technology and etherification reaction technology, and detailed calculation 200000 tons/year FCC gasoline etherification device design process. On the choice of catalytic light gasoline hydrogenation, etherification reaction and isomerization technology, through the analysis, summed up the best of catalytic cracking light gasoline etherification process flow.From engineering design aspects discusses the FCC gasoline light distillates etherification process flow and the equipment selection problem. Including the design of fractionation tower, hydrogenation reactors, etherification reactor device. This design uses a seri